Synthesis and structure of Sr14Zn1+xAs11 and Eu14Zn1+xAs11 (x ≤ 0.5). New members of the family of pnictides isotypic with Ca14AlSb11, exhibiting a new type of structural disorder

Systematic investigation of the ternary systems A–Zn–As (A = Sr, Eu) led to the discovery of two new ternary phases, Sr14Zn1+xAs11 and Eu14Zn1+xAs11 (x ≤ 0.5). Both title compounds were structurally characterized by single-crystal X-ray diffraction. The basic structure of these new arsenides is akin...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of solid state chemistry 2019-12, Vol.280 (C), Article 120990
Hauptverfasser:	Baranets, Sviatoslav, Darone, Gregory M., Bobev, Svilen
Format:	Artikel
Sprache:	eng
Schlagworte:	Arsenides Crystal structure Electronic structure INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY MATERIALS SCIENCE Single-crystal X-ray diffraction Zintl phases
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!