Hydrosilylation of an Iron(IV) Nitride Complex
The nitride ligand in iron(IV) complex PhB(MesIm)3Fe≡N reacts with excess H3SiPh to afford PhB(MesIm)3Fe(μ-H)3(SiHPh) as the major product, which has been structurally and spectroscopically characterized. Bulkier silane HaSiPh2 provides iron(II) amido complex PhB(MesIm)3FeN(H)(SiHPh2) as the initial...
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| Veröffentlicht in: | Inorganic chemistry 2019-12, Vol.59 (1) |
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| creator | Valdez-Moreira, Juan A. Millikan, Sean P. Gao, Xinfeng Carta, Veronica Chen, Chun-Hsing Smith, Jeremy M. |
| description | The nitride ligand in iron(IV) complex PhB(MesIm)3Fe≡N reacts with excess H3SiPh to afford PhB(MesIm)3Fe(μ-H)3(SiHPh) as the major product, which has been structurally and spectroscopically characterized. Bulkier silane HaSiPh2 provides iron(II) amido complex PhB(MesIm)3FeN(H)(SiHPh2) as the initial product of the reaction, with excess H2SiPh2 affording diamagnetic PhB(MesIm)3Fe(μ-H)3(SiPh2) as the major product. Lastly, unobserved iron(II) hydride PhB(MesIm)3Fe–H is implicated as an intermediate in this reaction, as suggested by the results of the reaction between iron(II) amido PhB(MesIm)3FeN(H)tBu and H3SiPh, which provides PhB(MesIm)3Fe(H)(μ-H)2(Si(NHtBu)Ph) as the sole product. |
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Bulkier silane HaSiPh2 provides iron(II) amido complex PhB(MesIm)3FeN(H)(SiHPh2) as the initial product of the reaction, with excess H2SiPh2 affording diamagnetic PhB(MesIm)3Fe(μ-H)3(SiPh2) as the major product. Lastly, unobserved iron(II) hydride PhB(MesIm)3Fe–H is implicated as an intermediate in this reaction, as suggested by the results of the reaction between iron(II) amido PhB(MesIm)3FeN(H)tBu and H3SiPh, which provides PhB(MesIm)3Fe(H)(μ-H)2(Si(NHtBu)Ph) as the sole product.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><language>eng</language><publisher>United States: American Chemical Society (ACS)</publisher><subject>Addition reactions ; Anions ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; Iron ; Ligands ; Nitrides</subject><ispartof>Inorganic chemistry, 2019-12, Vol.59 (1)</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000000232064725</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885</link.rule.ids><backlink>$$Uhttps://www.osti.gov/servlets/purl/1594033$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Valdez-Moreira, Juan A.</creatorcontrib><creatorcontrib>Millikan, Sean P.</creatorcontrib><creatorcontrib>Gao, Xinfeng</creatorcontrib><creatorcontrib>Carta, Veronica</creatorcontrib><creatorcontrib>Chen, Chun-Hsing</creatorcontrib><creatorcontrib>Smith, Jeremy M.</creatorcontrib><creatorcontrib>Indiana Univ., Bloomington, IN (United States)</creatorcontrib><title>Hydrosilylation of an Iron(IV) Nitride Complex</title><title>Inorganic chemistry</title><description>The nitride ligand in iron(IV) complex PhB(MesIm)3Fe≡N reacts with excess H3SiPh to afford PhB(MesIm)3Fe(μ-H)3(SiHPh) as the major product, which has been structurally and spectroscopically characterized. Bulkier silane HaSiPh2 provides iron(II) amido complex PhB(MesIm)3FeN(H)(SiHPh2) as the initial product of the reaction, with excess H2SiPh2 affording diamagnetic PhB(MesIm)3Fe(μ-H)3(SiPh2) as the major product. Lastly, unobserved iron(II) hydride PhB(MesIm)3Fe–H is implicated as an intermediate in this reaction, as suggested by the results of the reaction between iron(II) amido PhB(MesIm)3FeN(H)tBu and H3SiPh, which provides PhB(MesIm)3Fe(H)(μ-H)2(Si(NHtBu)Ph) as the sole product.</description><subject>Addition reactions</subject><subject>Anions</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>Iron</subject><subject>Ligands</subject><subject>Nitrides</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpjYuA0NDUy0DU1NIhgYeA0MACyDc3MLDkYuIqLswwMDCyNTcw4GfQ8KlOK8oszcypzEksy8_MU8tMUEvMUPIvy8zQ8wzQV_DJLijJTUhWc83MLclIreBhY0xJzilN5oTQ3g5Kba4izh25-cUlmfHFyZklqckZyfl5eanJJvKGppYmBsbExUYoAR4AzDg</recordid><startdate>20191226</startdate><enddate>20191226</enddate><creator>Valdez-Moreira, Juan A.</creator><creator>Millikan, Sean P.</creator><creator>Gao, Xinfeng</creator><creator>Carta, Veronica</creator><creator>Chen, Chun-Hsing</creator><creator>Smith, Jeremy M.</creator><general>American Chemical Society (ACS)</general><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000000232064725</orcidid></search><sort><creationdate>20191226</creationdate><title>Hydrosilylation of an Iron(IV) Nitride Complex</title><author>Valdez-Moreira, Juan A. ; Millikan, Sean P. ; Gao, Xinfeng ; Carta, Veronica ; Chen, Chun-Hsing ; Smith, Jeremy M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_15940333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Addition reactions</topic><topic>Anions</topic><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>Iron</topic><topic>Ligands</topic><topic>Nitrides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Valdez-Moreira, Juan A.</creatorcontrib><creatorcontrib>Millikan, Sean P.</creatorcontrib><creatorcontrib>Gao, Xinfeng</creatorcontrib><creatorcontrib>Carta, Veronica</creatorcontrib><creatorcontrib>Chen, Chun-Hsing</creatorcontrib><creatorcontrib>Smith, Jeremy M.</creatorcontrib><creatorcontrib>Indiana Univ., Bloomington, IN (United States)</creatorcontrib><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Valdez-Moreira, Juan A.</au><au>Millikan, Sean P.</au><au>Gao, Xinfeng</au><au>Carta, Veronica</au><au>Chen, Chun-Hsing</au><au>Smith, Jeremy M.</au><aucorp>Indiana Univ., Bloomington, IN (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrosilylation of an Iron(IV) Nitride Complex</atitle><jtitle>Inorganic chemistry</jtitle><date>2019-12-26</date><risdate>2019</risdate><volume>59</volume><issue>1</issue><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>The nitride ligand in iron(IV) complex PhB(MesIm)3Fe≡N reacts with excess H3SiPh to afford PhB(MesIm)3Fe(μ-H)3(SiHPh) as the major product, which has been structurally and spectroscopically characterized. 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| subjects | Addition reactions Anions INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Iron Ligands Nitrides |
| title | Hydrosilylation of an Iron(IV) Nitride Complex |
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