Selective Photo‐Oxygenation of Light Alkanes Using Iodine Oxides and Chloride

Partial oxidation of light alkanes to generate alkyl esters has been achieved under photochemical conditions using mixtures of iodine oxides and chloride salts in trifluoroacetic acid (HTFA). The reactions are catalytic in chloride and are successful using compact fluorescent light, but higher yield...

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Veröffentlicht in:	ChemCatChem 2019-10, Vol.11 (20), p.5045-5054
Hauptverfasser:	Liebov, Nichole S., Goldberg, Jonathan M., Boaz, Nicholas C., Coutard, Nathan, Kalman, Steven E., Zhuang, Thompson, Groves, John T., Gunnoe, T. Brent
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanes catalysis Chlorides Chlorine C−H functionalization Esters Ethane Fluorescence Iodine Mercury lamps methane Oxidation Oxidation resistance Oxygenation photochemistry Trifluoroacetates
Online-Zugang:	Volltext
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