The mechanism and kinetics of methyl isobutyl ketone synthesis from acetone over ion-exchanged hydroxyapatite

[Display omitted] •Acetone condensation was investigated over hydroxyapatite (HAP).•The rate-limiting step is the E1cB dehydration of diacetone alcohol.•The acid/base properties of HAP can be tuned by cation exchange.•Sr-HAP is 1.4x more active for acetone condensation than Ca-HAP. The synthesis of...

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Veröffentlicht in:	Journal of catalysis 2018-09, Vol.365 (C), p.174-183
Hauptverfasser:	Ho, Christopher R., Zheng, Steven, Shylesh, Sankaranarayanapillai, Bell, Alexis T.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acid-base strength Aldol condensation C[sbnd]C coupling CC coupling Green chemistry INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Online-Zugang:	Volltext
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