Water oxidation catalysis via immobilization of the dimanganese complex [Mn2(μ-O)2Cl(μ-O2CCH3)(bpy)2(H2O)](NO3)2 onto silica

Adsorption of a dinuclear μ-oxo bridged Mn complex onto mesoporous silica was observed when SBA15 was treated with an acetonitrile solution of [Mn2(μ-O)2Cl(μ-O2CCH3)(H2O)(bpy)2](NO3)2 (1). This complex was immobilized via the displacement of NO3(-) into solution, and characterization by spectroscopi...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2013-09, Vol.42 (34), p.12238-12247
Hauptverfasser: Rumberger, Evan M W, Ahn, Hyun S, Bell, Alexis T, Tilley, T Don
Format: Artikel
Sprache:eng
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