Brønsted–Evans–Polanyi relation for CO oxidation on metal oxides following the Mars–van Krevelen mechanism

Scaling relations are widely used to model catalytic reactions on metal surfaces, but they are less commonly applied to metal oxides. Oxygen vacancy formation energies have been suggested as a descriptor for the activity toward oxidation reactions via the Mars-van Krevelen mechanism. However, there...

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Veröffentlicht in:Journal of catalysis 2019-09, Vol.377 (C)
Hauptverfasser: Kropp, Thomas, Mavrikakis, Manos
Format: Artikel
Sprache:eng
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