An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements
The synthesis, structure, and spectroscopic characterization of the first transplutonium metal–organic framework (MOF) is described. The preparation and structure of Am‐GWMOF‐6, [Am2(C6H8O4)3(H2O)2][(C10H8N2)], is analogous to that of the isostructural trivalent lanthanide‐only containing material G...
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| Veröffentlicht in: | Angewandte Chemie 2019-11, Vol.131 (46), p.16660-16663 |
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| creator | Ridenour, J. August Surbella, Robert G. Gelis, Artem V. Koury, Daniel Poineau, Frederic Czerwinski, Kenneth R. Cahill, Christopher L. |
| description | The synthesis, structure, and spectroscopic characterization of the first transplutonium metal–organic framework (MOF) is described. The preparation and structure of Am‐GWMOF‐6, [Am2(C6H8O4)3(H2O)2][(C10H8N2)], is analogous to that of the isostructural trivalent lanthanide‐only containing material GWMOF‐6. The presented MOF architecture is used as a platform to probe Am3+ coordination chemistry and guest‐enhanced luminescent emission, whereas the framework itself provides a means to monitor the effects of self‐irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that MOFs provide in the structural and spectroscopic study of actinides.
Das erste Transplutonium‐MOF (Metall‐organisches Gerüst), [Am2(C6H8O4)3(H2O)2]⋅(C10H8N2), enthält dreiwertiges Americium und wird in Form von Am‐GWMOF‐6 erhalten. Es hat eine analoge Struktur wie das dreiwertige Lanthanoid‐MOF GWMOF‐6 und dient als Plattform zur Untersuchung der Am3+‐Koordinationschemie und der gastmolekülverstärkten Lumineszenzemission. |
| doi_str_mv | 10.1002/ange.201909988 |
| format | Article |
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Das erste Transplutonium‐MOF (Metall‐organisches Gerüst), [Am2(C6H8O4)3(H2O)2]⋅(C10H8N2), enthält dreiwertiges Americium und wird in Form von Am‐GWMOF‐6 erhalten. Es hat eine analoge Struktur wie das dreiwertige Lanthanoid‐MOF GWMOF‐6 und dient als Plattform zur Untersuchung der Am3+‐Koordinationschemie und der gastmolekülverstärkten Lumineszenzemission.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.201909988</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Actinides ; Americium ; Chemistry ; Irradiation ; Lumineszenz ; Metal-organic frameworks ; Metall-organische Gerüstverbindungen ; Metals ; Organic chemistry ; Radiation ; Röntgenbeugung ; Structural analysis ; Transplutoniumelemente</subject><ispartof>Angewandte Chemie, 2019-11, Vol.131 (46), p.16660-16663</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1898-623fbd9680a189e742d8bfbb3ba7f12328ff106fc623f29948d78b10ecf7c2e03</citedby><cites>FETCH-LOGICAL-c1898-623fbd9680a189e742d8bfbb3ba7f12328ff106fc623f29948d78b10ecf7c2e03</cites><orcidid>0000-0002-2015-3595 ; 0000000220153595</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fange.201909988$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fange.201909988$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/1567888$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Ridenour, J. August</creatorcontrib><creatorcontrib>Surbella, Robert G.</creatorcontrib><creatorcontrib>Gelis, Artem V.</creatorcontrib><creatorcontrib>Koury, Daniel</creatorcontrib><creatorcontrib>Poineau, Frederic</creatorcontrib><creatorcontrib>Czerwinski, Kenneth R.</creatorcontrib><creatorcontrib>Cahill, Christopher L.</creatorcontrib><title>An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements</title><title>Angewandte Chemie</title><description>The synthesis, structure, and spectroscopic characterization of the first transplutonium metal–organic framework (MOF) is described. The preparation and structure of Am‐GWMOF‐6, [Am2(C6H8O4)3(H2O)2][(C10H8N2)], is analogous to that of the isostructural trivalent lanthanide‐only containing material GWMOF‐6. The presented MOF architecture is used as a platform to probe Am3+ coordination chemistry and guest‐enhanced luminescent emission, whereas the framework itself provides a means to monitor the effects of self‐irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that MOFs provide in the structural and spectroscopic study of actinides.
Das erste Transplutonium‐MOF (Metall‐organisches Gerüst), [Am2(C6H8O4)3(H2O)2]⋅(C10H8N2), enthält dreiwertiges Americium und wird in Form von Am‐GWMOF‐6 erhalten. Es hat eine analoge Struktur wie das dreiwertige Lanthanoid‐MOF GWMOF‐6 und dient als Plattform zur Untersuchung der Am3+‐Koordinationschemie und der gastmolekülverstärkten Lumineszenzemission.</description><subject>Actinides</subject><subject>Americium</subject><subject>Chemistry</subject><subject>Irradiation</subject><subject>Lumineszenz</subject><subject>Metal-organic frameworks</subject><subject>Metall-organische Gerüstverbindungen</subject><subject>Metals</subject><subject>Organic chemistry</subject><subject>Radiation</subject><subject>Röntgenbeugung</subject><subject>Structural analysis</subject><subject>Transplutoniumelemente</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LwzAYh4MoOKdXz0XPnUnatYm3MrYpzD_gPIc0TWZmm8wkZey2jyD4DfdJ7Jjo0cv78sLz_Hj5AXCJ4ABBiG-4WcgBhohCSgk5Aj00xChO8mF-DHoQpmlMcEpPwZn3SwhhhnPaA1VhoqKRTgvdNrvt58iawLXRZhE9yMDr3fbryS240SKaON7ItXXvt1ERPdc8KOuaqBvRS2irzV6ZO278qm6DNV1cNK5lI03w5-BE8drLi5_dB6-T8Xx0F8-epvejYhYLRCiJM5yosqIZgby7ZZ7iipSqLJOS5wrhBBOlEMyU2IOY0pRUOSkRlELlAkuY9MHVIdf6oJkXOkjxJqwxUgSGhllOCOmg6wO0cvajlT6wpW2d6f5iOEEoJZAktKMGB0o4672Tiq2cbrjbMATZvm62r5v91t0J9CCsdS03_9CseJyO_9xvGZqGhw</recordid><startdate>20191111</startdate><enddate>20191111</enddate><creator>Ridenour, J. August</creator><creator>Surbella, Robert G.</creator><creator>Gelis, Artem V.</creator><creator>Koury, Daniel</creator><creator>Poineau, Frederic</creator><creator>Czerwinski, Kenneth R.</creator><creator>Cahill, Christopher L.</creator><general>Wiley Subscription Services, Inc</general><general>Wiley Blackwell (John Wiley & Sons)</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-2015-3595</orcidid><orcidid>https://orcid.org/0000000220153595</orcidid></search><sort><creationdate>20191111</creationdate><title>An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements</title><author>Ridenour, J. August ; Surbella, Robert G. ; Gelis, Artem V. ; Koury, Daniel ; Poineau, Frederic ; Czerwinski, Kenneth R. ; Cahill, Christopher L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1898-623fbd9680a189e742d8bfbb3ba7f12328ff106fc623f29948d78b10ecf7c2e03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Actinides</topic><topic>Americium</topic><topic>Chemistry</topic><topic>Irradiation</topic><topic>Lumineszenz</topic><topic>Metal-organic frameworks</topic><topic>Metall-organische Gerüstverbindungen</topic><topic>Metals</topic><topic>Organic chemistry</topic><topic>Radiation</topic><topic>Röntgenbeugung</topic><topic>Structural analysis</topic><topic>Transplutoniumelemente</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ridenour, J. August</creatorcontrib><creatorcontrib>Surbella, Robert G.</creatorcontrib><creatorcontrib>Gelis, Artem V.</creatorcontrib><creatorcontrib>Koury, Daniel</creatorcontrib><creatorcontrib>Poineau, Frederic</creatorcontrib><creatorcontrib>Czerwinski, Kenneth R.</creatorcontrib><creatorcontrib>Cahill, Christopher L.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ridenour, J. August</au><au>Surbella, Robert G.</au><au>Gelis, Artem V.</au><au>Koury, Daniel</au><au>Poineau, Frederic</au><au>Czerwinski, Kenneth R.</au><au>Cahill, Christopher L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements</atitle><jtitle>Angewandte Chemie</jtitle><date>2019-11-11</date><risdate>2019</risdate><volume>131</volume><issue>46</issue><spage>16660</spage><epage>16663</epage><pages>16660-16663</pages><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>The synthesis, structure, and spectroscopic characterization of the first transplutonium metal–organic framework (MOF) is described. The preparation and structure of Am‐GWMOF‐6, [Am2(C6H8O4)3(H2O)2][(C10H8N2)], is analogous to that of the isostructural trivalent lanthanide‐only containing material GWMOF‐6. The presented MOF architecture is used as a platform to probe Am3+ coordination chemistry and guest‐enhanced luminescent emission, whereas the framework itself provides a means to monitor the effects of self‐irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that MOFs provide in the structural and spectroscopic study of actinides.
Das erste Transplutonium‐MOF (Metall‐organisches Gerüst), [Am2(C6H8O4)3(H2O)2]⋅(C10H8N2), enthält dreiwertiges Americium und wird in Form von Am‐GWMOF‐6 erhalten. Es hat eine analoge Struktur wie das dreiwertige Lanthanoid‐MOF GWMOF‐6 und dient als Plattform zur Untersuchung der Am3+‐Koordinationschemie und der gastmolekülverstärkten Lumineszenzemission.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ange.201909988</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-2015-3595</orcidid><orcidid>https://orcid.org/0000000220153595</orcidid></addata></record> |
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| subjects | Actinides Americium Chemistry Irradiation Lumineszenz Metal-organic frameworks Metall-organische Gerüstverbindungen Metals Organic chemistry Radiation Röntgenbeugung Structural analysis Transplutoniumelemente |
| title | An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements |
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