Chemistry in confined spaces: reactivity of the Zn-MOF-74 channels

Using infrared spectroscopy combined with ab initio methods we study reactions of H 2 O and CO inside the confined spaces of Zn-MOF-74 channels. Our results show that, once the water dissociation reaction H 2 O OH + H takes place at the metal centers, the addition of 40 Torr of CO at 200 C starts th...

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Veröffentlicht in:	Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2016-01, Vol.4 (34), p.13176-13182
Hauptverfasser:	Zuluaga, S, Fuentes-Fernandez, E. M. A, Tan, K, Arter, C. A, Li, J, Chabal, Y. J, Thonhauser, T
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Channels Chemistry Cobalt Confined environments Crystal structure Energy & Fuels Formic acid Infrared spectroscopy Materials Science Zinc
Online-Zugang:	Volltext
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