Simultaneous Bottom‐Up Interfacial and Bulk Defect Passivation in Highly Efficient Planar Perovskite Solar Cells using Nonconjugated Small‐Molecule Electrolytes

Recent perovskite solar cell (PSC) advances have pursued strategies for reducing interfacial energetic mismatches to mitigate energy losses, as well as to minimize interfacial and bulk defects and ion vacancies to maximize charge transfer. Here nonconjugated multi‐zwitterionic small‐molecule electro...

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Veröffentlicht in:Advanced materials (Weinheim) 2019-10, Vol.31 (40), p.e1903239-n/a
Hauptverfasser: Zheng, Ding, Peng, Ruixiang, Wang, Gang, Logsdon, Jenna Leigh, Wang, Binghao, Hu, Xiaobing, Chen, Yao, Dravid, Vinayak P., Wasielewski, Michael R., Yu, Junsheng, Huang, Wei, Ge, Ziyi, Marks, Tobin J., Facchetti, Antonio
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container_issue 40
container_start_page e1903239
container_title Advanced materials (Weinheim)
container_volume 31
creator Zheng, Ding
Peng, Ruixiang
Wang, Gang
Logsdon, Jenna Leigh
Wang, Binghao
Hu, Xiaobing
Chen, Yao
Dravid, Vinayak P.
Wasielewski, Michael R.
Yu, Junsheng
Huang, Wei
Ge, Ziyi
Marks, Tobin J.
Facchetti, Antonio
description Recent perovskite solar cell (PSC) advances have pursued strategies for reducing interfacial energetic mismatches to mitigate energy losses, as well as to minimize interfacial and bulk defects and ion vacancies to maximize charge transfer. Here nonconjugated multi‐zwitterionic small‐molecule electrolytes (NSEs) are introduced, which act not only as charge‐extracting layers for barrier‐free charge collection at planar triple cation PSC cathodes but also passivate charged defects at the perovskite bulk/interface via a spontaneous bottom‐up passivation effect. Implementing these synergistic properties affords NSE‐based planar PSCs that deliver a remarkable power conversion efficiency of 21.18% with a maximum VOC = 1.19 V, in combination with suppressed hysteresis and enhanced environmental, thermal, and light‐soaking stability. Thus, this work demonstrates that the bottom‐up, simultaneous interfacial and bulk trap passivation using NSE modifiers is a promising strategy to overcome outstanding issues impeding further PSC advances. Nonconjugated multi‐zwitterionic small‐molecule electrolyte (NSE) molecules in perovskite solar cells (PSCs) act not only as both charge‐extracting layers for barrier‐free cathode charge collection but also as charged defect fillers in perovskite bulk and interfaces by spontaneous bottom‐up passivation. Thus, the NSE‐based PSCs deliver PCEs as high as 21.18% with an ultrahigh VOC of 1.19 V, suppressed hysteresis, and enhanced stability.
doi_str_mv 10.1002/adma.201903239
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subjects bottom‐up passivation
Charge transfer
Defects
Electrolytes
Electrolytic cells
electron‐transport layer
Energy conservation
Energy conversion efficiency
Interface stability
Materials science
Passivity
perovskite solar cells
Perovskites
Photovoltaic cells
Solar cells
zwitterions
title Simultaneous Bottom‐Up Interfacial and Bulk Defect Passivation in Highly Efficient Planar Perovskite Solar Cells using Nonconjugated Small‐Molecule Electrolytes
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