Copper(I) and copper(II) metallacycles as catalysts for microwave assisted selective oxidation of cyclohexane

Cu(I) and Cu(II) metallocycles were prepared with pyrazolates having CF3 or NO2 groups in the 3 and 5 positions. According to similar reaction routes, they yielded a hydrated hexanuclear metallocycle [(µ-pz)Cu(µ-OH]6 and a dinuclear compound with an N2-Cu2(PPh3)2-N2 boat shaped core, respectively. B...

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Veröffentlicht in:Polyhedron 2017-09, Vol.134 (C), p.143-152
Hauptverfasser: Galassi, Rossana, Simon, Oumarou Camille, Burini, Alfredo, Tosi, Giorgio, Conti, Carla, Graiff, Claudia, Martins, Nuno M.R., Guedes da Silva, M. Fátima C., Pombeiro, Armando J.L., Martins, Luísa M.D.R.S.
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Sprache:eng
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