Copper(I) and copper(II) metallacycles as catalysts for microwave assisted selective oxidation of cyclohexane
Cu(I) and Cu(II) metallocycles were prepared with pyrazolates having CF3 or NO2 groups in the 3 and 5 positions. According to similar reaction routes, they yielded a hydrated hexanuclear metallocycle [(µ-pz)Cu(µ-OH]6 and a dinuclear compound with an N2-Cu2(PPh3)2-N2 boat shaped core, respectively. B...
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Veröffentlicht in: | Polyhedron 2017-09, Vol.134 (C), p.143-152 |
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Sprache: | eng |
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