Properties of perhalogenated {closo-B10} and {closo-B11} multiply charged anions and a critical comparison with {closo-B12} in the gas and the condensed phase

closo-Borate anions [closo-BnXn]2– are part of the most famous textbook examples of polyhedral compounds. Substantial differences in their reactivity and interactions with other compounds depending on the substituent X and cluster size n have been recognized, which favor specific closo-borates for d...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2018-11, Vol.21 (11)
Hauptverfasser: Warneke, Jonas, Konieczka, Szymon Z., Hou, Gao-Lei, Aprà, Edoardo, Kerpen, Christoph, Keppner, Fabian, Schäfer, Thomas C., Deckert, Michael, Yang, Zheng, Bylaska, Eric J., Johnson, Grant E., Laskin, Julia, Xantheas, Sotiris S., Wang, Xue-Bin, Finze, Maik
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Sprache:eng
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