A Redox-Active Bistable Molecular Switch Mounted inside a Metal–Organic Framework
We describe the incorporation of a bistable mechanically interlocked molecule (MIM) into a robust Zr-based metal–organic framework (MOF), NU-1000, by employing a post-synthetic functionalization protocol. On average, close to two bistable [2]catenanes can be incorporated per repeating unit of...
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| Veröffentlicht in: | Journal of the American Chemical Society 2016-11, Vol.138 (43), p.14242-14245 |
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| container_end_page | 14245 |
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| container_issue | 43 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 138 |
| creator | Chen, Qishui Sun, Junling Li, Peng Hod, Idan Moghadam, Peyman Z Kean, Zachary S Snurr, Randall Q Hupp, Joseph T Farha, Omar K Stoddart, J. Fraser |
| description | We describe the incorporation of a bistable mechanically interlocked molecule (MIM) into a robust Zr-based metal–organic framework (MOF), NU-1000, by employing a post-synthetic functionalization protocol. On average, close to two bistable [2]catenanes can be incorporated per repeating unit of the hexagonal channels of NU-1000. The reversible redox-switching of the bistable [2]catenanes is retained inside the MOF, as evidenced by solid-state UV-vis-NIR reflectance spectroscopy and cyclic voltammetry. This research demonstrates that bistable MIMs are capable of exhibiting robust dynamics inside the nanopores of a MOF. |
| doi_str_mv | 10.1021/jacs.6b09880 |
| format | Article |
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Soc</addtitle><date>2016-11-02</date><risdate>2016</risdate><volume>138</volume><issue>43</issue><spage>14242</spage><epage>14245</epage><pages>14242-14245</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>We describe the incorporation of a bistable mechanically interlocked molecule (MIM) into a robust Zr-based metal–organic framework (MOF), NU-1000, by employing a post-synthetic functionalization protocol. On average, close to two bistable [2]catenanes can be incorporated per repeating unit of the hexagonal channels of NU-1000. The reversible redox-switching of the bistable [2]catenanes is retained inside the MOF, as evidenced by solid-state UV-vis-NIR reflectance spectroscopy and cyclic voltammetry. 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| issn | 0002-7863 1520-5126 |
| language | eng |
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| source | ACS Publications |
| subjects | Chemistry |
| title | A Redox-Active Bistable Molecular Switch Mounted inside a Metal–Organic Framework |
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