Controlled cis Labilization of CO from Manganese(I) Mixed Carbonyl/Isocyanide Complexes: An Entry Point to Coordinatively Unsaturated Metallo-Lewis Acids

Presented herein is a general design strategy for the formation of coordinatively unsaturated Mn­(I) fragments via the cis labilization of CO using metal carboxylates and subsequent deprotection by a range of abstraction agents. A consistent trend is observed in the ability of carboxylate ligands to...

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Veröffentlicht in:	Organometallics 2017-01, Vol.36 (2), p.363-371
Hauptverfasser:	Agnew, Douglas W, Moore, Curtis E, Rheingold, Arnold L, Figueroa, Joshua S
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry
Online-Zugang:	Volltext
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