Acid-functionalized mesoporous carbons for the continuous production of 5-hydroxymethylfurfural
The stability of solid acid catalysts is essential in the development of sustainable biomass conversion processes. In this report we study the activity and stability of acid-functionalized periodic mesoporous carbons (CMK-3 and CMK-5) for the continuous production of 5-hydroxymethylfurfural from fru...
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| Veröffentlicht in: | Journal of molecular catalysis. A, Chemical Chemical, 2016-01, Vol.422 (C) |
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| creator | Gallo, Jean R. Alamillo, Ricardo Dumesic, James A. |
| description | The stability of solid acid catalysts is essential in the development of sustainable biomass conversion processes. In this report we study the activity and stability of acid-functionalized periodic mesoporous carbons (CMK-3 and CMK-5) for the continuous production of 5-hydroxymethylfurfural from fructose. The acid-functionalized mesoporous carbon catalysts show comparable selectivities and turnover frequency (TOF) to that of propylsulfonic acid functionalized SBA-15. However, the first-order deactivation rate coefficient of the carbon-based materials are up to 60 times more stable than that for the acid-functionalized SBA-15 catalyst and up to 3 times more stable than commercial Nafion SAC-13. Of the catalysts studied, phenylsulfonic acid CMK-5 showed both the highest TOF for HMF production and lowest deactivation rate coefficient. |
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In this report we study the activity and stability of acid-functionalized periodic mesoporous carbons (CMK-3 and CMK-5) for the continuous production of 5-hydroxymethylfurfural from fructose. The acid-functionalized mesoporous carbon catalysts show comparable selectivities and turnover frequency (TOF) to that of propylsulfonic acid functionalized SBA-15. However, the first-order deactivation rate coefficient of the carbon-based materials are up to 60 times more stable than that for the acid-functionalized SBA-15 catalyst and up to 3 times more stable than commercial Nafion SAC-13. Of the catalysts studied, phenylsulfonic acid CMK-5 showed both the highest TOF for HMF production and lowest deactivation rate coefficient.</description><identifier>ISSN: 1381-1169</identifier><identifier>EISSN: 1873-314X</identifier><language>eng</language><publisher>United States: Elsevier</publisher><subject>biomass conversion ; deactivation ; heterogeneous catalysis ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; mesoporous carbon5-hydroxymethylfurfural</subject><ispartof>Journal of molecular catalysis. 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A, Chemical</title><description>The stability of solid acid catalysts is essential in the development of sustainable biomass conversion processes. In this report we study the activity and stability of acid-functionalized periodic mesoporous carbons (CMK-3 and CMK-5) for the continuous production of 5-hydroxymethylfurfural from fructose. The acid-functionalized mesoporous carbon catalysts show comparable selectivities and turnover frequency (TOF) to that of propylsulfonic acid functionalized SBA-15. However, the first-order deactivation rate coefficient of the carbon-based materials are up to 60 times more stable than that for the acid-functionalized SBA-15 catalyst and up to 3 times more stable than commercial Nafion SAC-13. Of the catalysts studied, phenylsulfonic acid CMK-5 showed both the highest TOF for HMF production and lowest deactivation rate coefficient.</description><subject>biomass conversion</subject><subject>deactivation</subject><subject>heterogeneous catalysis</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>mesoporous carbon5-hydroxymethylfurfural</subject><issn>1381-1169</issn><issn>1873-314X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqNTksKwjAUDKLg9w7BfaAhba1LEcUDuHBXaj4kkuaVfMB6eqN4AGFgBubDTNCCNjtGGC1v06xZQwml9X6OliE8iqIoWUkXqD1wI4hKjkcDrrPmJQXuZYABPKSAeefv4AJW4HHUEnNw0bj0sQYPIn1rGBSuiB6Fh-fYy6hHq5LP6OwazVRng9z8eIW259P1eCEQomkDN1FynUed5LGlVf5Ea_ZX6A1A0Ueu</recordid><startdate>20160111</startdate><enddate>20160111</enddate><creator>Gallo, Jean R.</creator><creator>Alamillo, Ricardo</creator><creator>Dumesic, James A.</creator><general>Elsevier</general><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000000329372628</orcidid></search><sort><creationdate>20160111</creationdate><title>Acid-functionalized mesoporous carbons for the continuous production of 5-hydroxymethylfurfural</title><author>Gallo, Jean R. ; Alamillo, Ricardo ; Dumesic, James A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_15341163</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>biomass conversion</topic><topic>deactivation</topic><topic>heterogeneous catalysis</topic><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>mesoporous carbon5-hydroxymethylfurfural</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gallo, Jean R.</creatorcontrib><creatorcontrib>Alamillo, Ricardo</creatorcontrib><creatorcontrib>Dumesic, James A.</creatorcontrib><creatorcontrib>Univ. of Wisconsin, Madison, WI (United States)</creatorcontrib><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Journal of molecular catalysis. A, Chemical</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gallo, Jean R.</au><au>Alamillo, Ricardo</au><au>Dumesic, James A.</au><aucorp>Univ. of Wisconsin, Madison, WI (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Acid-functionalized mesoporous carbons for the continuous production of 5-hydroxymethylfurfural</atitle><jtitle>Journal of molecular catalysis. A, Chemical</jtitle><date>2016-01-11</date><risdate>2016</risdate><volume>422</volume><issue>C</issue><issn>1381-1169</issn><eissn>1873-314X</eissn><abstract>The stability of solid acid catalysts is essential in the development of sustainable biomass conversion processes. In this report we study the activity and stability of acid-functionalized periodic mesoporous carbons (CMK-3 and CMK-5) for the continuous production of 5-hydroxymethylfurfural from fructose. The acid-functionalized mesoporous carbon catalysts show comparable selectivities and turnover frequency (TOF) to that of propylsulfonic acid functionalized SBA-15. However, the first-order deactivation rate coefficient of the carbon-based materials are up to 60 times more stable than that for the acid-functionalized SBA-15 catalyst and up to 3 times more stable than commercial Nafion SAC-13. Of the catalysts studied, phenylsulfonic acid CMK-5 showed both the highest TOF for HMF production and lowest deactivation rate coefficient.</abstract><cop>United States</cop><pub>Elsevier</pub><orcidid>https://orcid.org/0000000329372628</orcidid><oa>free_for_read</oa></addata></record> |
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| issn | 1381-1169 1873-314X |
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| source | Elsevier ScienceDirect Journals |
| subjects | biomass conversion deactivation heterogeneous catalysis INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY mesoporous carbon5-hydroxymethylfurfural |
| title | Acid-functionalized mesoporous carbons for the continuous production of 5-hydroxymethylfurfural |
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