The Allosteric Regulation of Axial/Rhombic Population in a “Type 1” Copper Site: Multi-Edge X-ray Absorption Spectroscopic and Density Functional Studies of Pseudoazurin

The co-existence of “axial” and “rhombic” coordination environments has been demonstrated in a “Type 1” copper site of Pseudoazurin. This observation opens up previously not considered interpretations for the relationship between geometry and electronic structure of the four coordinate copper site....

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2015-12, Vol.88 (12), p.1642-1652
Hauptverfasser: Yamaguchi, Takahide, Yano, Junko, Yachandra, Vittal K, Nihei, Yuko, Togashi, Hiromi, Szilagyi, Robert K, Kohzuma, Takamitsu
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Sprache:eng
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