Oxidation Characteristics of Two FeCrAl Alloys in Air and Steam from 800°C to 1300°C
Iron-chromium-aluminum (FeCrAl) alloys are being investigated as cladding material for urania nuclear fuel in light water power reactors. One extraordinary attribute of the FeCrAl alloys is their resistance to attack by air and steam up to their melting point. It was of interest to study the kinetic...
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| Veröffentlicht in: | JOM (1989) 2018-08, Vol.70 (8), p.1484-1492 |
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| creator | Rebak, Raul B. Gupta, Vipul K. Larsen, Michael |
| description | Iron-chromium-aluminum (FeCrAl) alloys are being investigated as cladding material for urania nuclear fuel in light water power reactors. One extraordinary attribute of the FeCrAl alloys is their resistance to attack by air and steam up to their melting point. It was of interest to study the kinetics of oxidation of FeCrAl from 800°C to 1300°C in air and in steam to determine how the oxides evolve to provide protection to the alloys. The two investigated alloys were APMT (Fe-21Cr-5Al-3Mo) and C26M (Fe-12Cr-6Al-2Mo). Results show that both alloys had similar oxidation kinetics despite their different chemical compositions. For the testing times, the oxidation rate was higher in air than in steam at the higher temperatures (1100–1300°C) and higher in steam than in air at the lower temperatures (800–1100°C). In the lower temperature range, the surface oxide consisted of two layers, an internal layer rich in aluminum and an external layer containing Al, Cr, and Fe. In the higher temperature range, the oxide was a single layer of alumina (no Cr, no Fe, no Mo). |
| doi_str_mv | 10.1007/s11837-018-2979-9 |
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One extraordinary attribute of the FeCrAl alloys is their resistance to attack by air and steam up to their melting point. It was of interest to study the kinetics of oxidation of FeCrAl from 800°C to 1300°C in air and in steam to determine how the oxides evolve to provide protection to the alloys. The two investigated alloys were APMT (Fe-21Cr-5Al-3Mo) and C26M (Fe-12Cr-6Al-2Mo). Results show that both alloys had similar oxidation kinetics despite their different chemical compositions. For the testing times, the oxidation rate was higher in air than in steam at the higher temperatures (1100–1300°C) and higher in steam than in air at the lower temperatures (800–1100°C). In the lower temperature range, the surface oxide consisted of two layers, an internal layer rich in aluminum and an external layer containing Al, Cr, and Fe. In the higher temperature range, the oxide was a single layer of alumina (no Cr, no Fe, no Mo).</description><identifier>ISSN: 1047-4838</identifier><identifier>EISSN: 1543-1851</identifier><identifier>DOI: 10.1007/s11837-018-2979-9</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Alumina ; Aluminum ; Aluminum oxide ; Chemical attack ; Chemical composition ; Chemistry/Food Science ; Chromium ; Cladding ; Corrosion Behavior ; Discount coupons ; Earth Sciences ; Engineering ; Environment ; Ferrous alloys ; Iron ; Light water ; MATERIALS SCIENCE ; Melting points ; Microscopy ; Molybdenum ; Nuclear fuels ; Nuclear Materials ; Nuclear reactors ; Organic chemistry ; Oxidation ; Oxidation rate ; Physics ; Powder metallurgy ; Power reactors ; Reaction kinetics ; Supercritical CO2 ; Temperature ; Zirconium alloys</subject><ispartof>JOM (1989), 2018-08, Vol.70 (8), p.1484-1492</ispartof><rights>The Author(s) 2018</rights><rights>Copyright Springer Science & Business Media Aug 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3019-d59d63c2d038b811ac21a223cb99c6aadd2e0dea9a46727c4cded3f7d02a671c3</citedby><cites>FETCH-LOGICAL-c3019-d59d63c2d038b811ac21a223cb99c6aadd2e0dea9a46727c4cded3f7d02a671c3</cites><orcidid>0000-0002-8070-4475 ; 0000000280704475</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11837-018-2979-9$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11837-018-2979-9$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>230,314,780,784,885,27915,27916,41479,42548,51310</link.rule.ids><backlink>$$Uhttps://www.osti.gov/servlets/purl/1511459$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Rebak, Raul B.</creatorcontrib><creatorcontrib>Gupta, Vipul K.</creatorcontrib><creatorcontrib>Larsen, Michael</creatorcontrib><creatorcontrib>General Electric Co., Niskayuna, NY (United States)</creatorcontrib><title>Oxidation Characteristics of Two FeCrAl Alloys in Air and Steam from 800°C to 1300°C</title><title>JOM (1989)</title><addtitle>JOM</addtitle><description>Iron-chromium-aluminum (FeCrAl) alloys are being investigated as cladding material for urania nuclear fuel in light water power reactors. 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In the higher temperature range, the oxide was a single layer of alumina (no Cr, no Fe, no Mo).</description><subject>Alumina</subject><subject>Aluminum</subject><subject>Aluminum oxide</subject><subject>Chemical attack</subject><subject>Chemical composition</subject><subject>Chemistry/Food Science</subject><subject>Chromium</subject><subject>Cladding</subject><subject>Corrosion Behavior</subject><subject>Discount coupons</subject><subject>Earth Sciences</subject><subject>Engineering</subject><subject>Environment</subject><subject>Ferrous alloys</subject><subject>Iron</subject><subject>Light water</subject><subject>MATERIALS SCIENCE</subject><subject>Melting points</subject><subject>Microscopy</subject><subject>Molybdenum</subject><subject>Nuclear fuels</subject><subject>Nuclear Materials</subject><subject>Nuclear reactors</subject><subject>Organic chemistry</subject><subject>Oxidation</subject><subject>Oxidation rate</subject><subject>Physics</subject><subject>Powder metallurgy</subject><subject>Power reactors</subject><subject>Reaction kinetics</subject><subject>Supercritical CO2</subject><subject>Temperature</subject><subject>Zirconium alloys</subject><issn>1047-4838</issn><issn>1543-1851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kLFOwzAURSMEEqXwAWwWzAY_O4ntsYooIFXqQGG1XNuhqdK42Kmgf8U38GW4BImJ6d3h3Kunk2WXQG6AEH4bAQTjmIDAVHKJ5VE2giJnGEQBxymTnONcMHGancW4JqmTSxhlL_OPxuq-8R2qVjpo07vQxL4xEfkaLd49mroqTFo0aVu_j6jp0KQJSHcWPfVOb1Ad_AYJQr4-K9R7BOwnnmcntW6ju_i94-x5ereoHvBsfv9YTWbYMAIS20LakhlqCRNLAaANBU0pM0spTam1tdQR67TUeckpN7mxzrKaW0J1ycGwcXY17Pr0s4qm6Z1ZGd91zvQKCoC8kAm6HqBt8G87F3u19rvQpb8UTY4kL7goEwUDZYKPMbhabUOz0WGvgKiDYzU4VsmxOjhWh2U6dGJiu1cX_pb_L30DWHF9Yg</recordid><startdate>20180801</startdate><enddate>20180801</enddate><creator>Rebak, Raul B.</creator><creator>Gupta, Vipul K.</creator><creator>Larsen, Michael</creator><general>Springer US</general><general>Springer Nature B.V</general><general>Springer</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>4T-</scope><scope>4U-</scope><scope>7SR</scope><scope>7TA</scope><scope>7WY</scope><scope>7XB</scope><scope>883</scope><scope>88I</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8FL</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FRNLG</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K60</scope><scope>K6~</scope><scope>KB.</scope><scope>L.-</scope><scope>M0F</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>S0X</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-8070-4475</orcidid><orcidid>https://orcid.org/0000000280704475</orcidid></search><sort><creationdate>20180801</creationdate><title>Oxidation Characteristics of Two FeCrAl Alloys in Air and Steam from 800°C to 1300°C</title><author>Rebak, Raul B. ; 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One extraordinary attribute of the FeCrAl alloys is their resistance to attack by air and steam up to their melting point. It was of interest to study the kinetics of oxidation of FeCrAl from 800°C to 1300°C in air and in steam to determine how the oxides evolve to provide protection to the alloys. The two investigated alloys were APMT (Fe-21Cr-5Al-3Mo) and C26M (Fe-12Cr-6Al-2Mo). Results show that both alloys had similar oxidation kinetics despite their different chemical compositions. For the testing times, the oxidation rate was higher in air than in steam at the higher temperatures (1100–1300°C) and higher in steam than in air at the lower temperatures (800–1100°C). In the lower temperature range, the surface oxide consisted of two layers, an internal layer rich in aluminum and an external layer containing Al, Cr, and Fe. In the higher temperature range, the oxide was a single layer of alumina (no Cr, no Fe, no Mo).</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11837-018-2979-9</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-8070-4475</orcidid><orcidid>https://orcid.org/0000000280704475</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Alumina Aluminum Aluminum oxide Chemical attack Chemical composition Chemistry/Food Science Chromium Cladding Corrosion Behavior Discount coupons Earth Sciences Engineering Environment Ferrous alloys Iron Light water MATERIALS SCIENCE Melting points Microscopy Molybdenum Nuclear fuels Nuclear Materials Nuclear reactors Organic chemistry Oxidation Oxidation rate Physics Powder metallurgy Power reactors Reaction kinetics Supercritical CO2 Temperature Zirconium alloys |
| title | Oxidation Characteristics of Two FeCrAl Alloys in Air and Steam from 800°C to 1300°C |
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