Catalytic Silylation of N 2 and Synthesis of NH 3 and N 2 H 4 by Net Hydrogen Atom Transfer Reactions Using a Chromium P 4 Macrocycle

We report the first discrete molecular Cr-based catalysts for the reduction of N . This study is focused on the reactivity of the Cr-N complex, trans-[Cr(N ) (P N )] (P Cr(N ) ), bearing a 16-membered tetraphosphine macrocycle. The architecture of the [16]-P N ligand is critical to preserve the stru...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-02, Vol.140 (7), p.2528-2536
Hauptverfasser:	Kendall, Alexander J, Johnson, Samantha I, Bullock, R Morris, Mock, Michael T
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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