Li 3 BN 2 as a Transition Metal Free, High Capacity Cathode for Li-ion Batteries
Li3BN2 is investigated for the first time as a transition metal free, high capacity cathode material for Li-ion batteries. It is shown that α-Li3BN2 can exhibit a specific capacity of 890 mA h g-1 with the charge storage mechanism associated with the valence state change of N ions in the BN2 anion....
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| Veröffentlicht in: | ChemElectroChem 2018-01, Vol.6 (2) |
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| container_title | ChemElectroChem |
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| creator | Emani, Satyanarayana Liu, Caihong Ashuri, Maziar Sahni, Karan Wu, Jinpeng Yang, Wanli Németh, Károly Shaw, Leon L. |
| description | Li3BN2 is investigated for the first time as a transition metal free, high capacity cathode material for Li-ion batteries. It is shown that α-Li3BN2 can exhibit a specific capacity of 890 mA h g-1 with the charge storage mechanism associated with the valence state change of N ions in the BN2 anion. The particular capacity demonstrated in this study is the highest one ever reported in literature for an intercalation-type cathode material. Moreover, using the valence state change of N ions as a charge storage mechanism opens the door for designing additional high performance, transition metal free electrodes in the future. |
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It is shown that α-Li3BN2 can exhibit a specific capacity of 890 mA h g-1 with the charge storage mechanism associated with the valence state change of N ions in the BN2 anion. The particular capacity demonstrated in this study is the highest one ever reported in literature for an intercalation-type cathode material. Moreover, using the valence state change of N ions as a charge storage mechanism opens the door for designing additional high performance, transition metal free electrodes in the future.</abstract><cop>United States</cop><pub>ChemPubSoc Europe</pub><orcidid>https://orcid.org/0000000221701573</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Cathodes ENERGY STORAGE Li-ion batteries Li3BN2 MATERIALS SCIENCE Transition metal free electrodes |
| title | Li 3 BN 2 as a Transition Metal Free, High Capacity Cathode for Li-ion Batteries |
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