Models for Deep Hydrodesulfurization of Alkylated Benzothiophenes. Reductive Cleavage of C−S Bonds Mediated by Precoordination of Manganese Tricarbonyl to the Carbocyclic Ring

The reduction of (η6-benzothiophene)Mn(CO)3 + with cobaltocene under CO leads to insertion of the Mn(CO)4 - fragment into the C(aryl)−S bond to afford a neutral bimetallic complex. When there are methyl substituents at the 2,3-, 2,7-, or 3,7-positions, the regioselectivity and product distribution i...

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Veröffentlicht in:	Organometallics 2002-03, Vol.21 (6), p.1262-1270
Hauptverfasser:	Li, Huazhi, Yu, Kunquan, Watson, Eric J, Virkaitis, Kurtis L, D'Acchioli, Jason S, Carpenter, Gene B, Sweigart, D. A, Czech, Paul T, Overly, Kenneth R, Coughlin, Fred
Format:	Artikel
Sprache:	eng
Schlagworte:	CHEMICAL BONDS CLEAVAGE DESULFURIZATION ENVIRONMENTAL MOLECULAR SCIENCES LABORATORY INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MANGANESE CARBONATES REDUCTION THIONAPHTHENES
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