Thermodynamic Studies on a Hydrogen Bonded Acidic 3,5-Bis(trifluoromethyl)phenol-functionalized Polymer as a Gas Chromatography Stationary Phase for Selectively Speciating Chemical Warfare Agents
We describe for the first time hydrogen bonded acid (HBA) polymer, poly{methyl[3-(2-hydroxyl, 4,6-bistrifluoromethyl)phenyl]propylsiloxane}, (DKAP), as stationary phase for gas chromatography (μGC) of organophosphate (OP), chemical warfare agent (CWA) surrogates, dimethylmethylphosphonate (DMMP), di...
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| Veröffentlicht in: | Analytical Sciences 2019/06/10, Vol.35(6), pp.671-677 |
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| creator | READ, Douglas H. ACHYUTHAN, Komandoor E. FIX, Cory S. MANGINELL, Ronald P. MOORMAN, Matthew W. SIMONSON, Robert J. WHEELER, David R. WHITING, Joshua J. |
| description | We describe for the first time hydrogen bonded acid (HBA) polymer, poly{methyl[3-(2-hydroxyl, 4,6-bistrifluoromethyl)phenyl]propylsiloxane}, (DKAP), as stationary phase for gas chromatography (μGC) of organophosphate (OP), chemical warfare agent (CWA) surrogates, dimethylmethylphosphonate (DMMP), diisopropylmethylphosphonate (DIMP), diethylmethylphosphonate (DEMP), and trimethylphosphate (TMP), with high selectivity. Absorption of OPs to DKAP was one-to-several orders of magnitude higher relative to commercial polar, mid-polar, and nonpolar stationary phases. We also present for the first-time thermodynamic studies on the absorption of OP vapors and quantitative binding energy data for interactions with various stationary phases. These data help to identify the best pair of hetero-polar columns for a two-dimensional GC system, employing a nonpolar stationary phase as GC1 and DKAP as the GC2 stationary phase, for selective and rapid field detection of CWAs. |
| doi_str_mv | 10.2116/analsci.18P537 |
| format | Article |
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(SNL-NM), Albuquerque, NM (United States)</creatorcontrib><description>We describe for the first time hydrogen bonded acid (HBA) polymer, poly{methyl[3-(2-hydroxyl, 4,6-bistrifluoromethyl)phenyl]propylsiloxane}, (DKAP), as stationary phase for gas chromatography (μGC) of organophosphate (OP), chemical warfare agent (CWA) surrogates, dimethylmethylphosphonate (DMMP), diisopropylmethylphosphonate (DIMP), diethylmethylphosphonate (DEMP), and trimethylphosphate (TMP), with high selectivity. Absorption of OPs to DKAP was one-to-several orders of magnitude higher relative to commercial polar, mid-polar, and nonpolar stationary phases. We also present for the first-time thermodynamic studies on the absorption of OP vapors and quantitative binding energy data for interactions with various stationary phases. These data help to identify the best pair of hetero-polar columns for a two-dimensional GC system, employing a nonpolar stationary phase as GC1 and DKAP as the GC2 stationary phase, for selective and rapid field detection of CWAs.</description><identifier>ISSN: 0910-6340</identifier><identifier>EISSN: 1348-2246</identifier><identifier>DOI: 10.2116/analsci.18P537</identifier><identifier>PMID: 30773510</identifier><language>eng</language><publisher>Singapore: The Japan Society for Analytical Chemistry</publisher><subject>Absorption ; Analytical Chemistry ; Bonding agents ; Chemical warfare ; Chemical warfare agents ; Chemistry ; Chromatography ; DKAP ; Gas chromatography ; GC stationary phase ; hydrogen bonded acid ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; Organic chemistry ; Organophosphates ; Phenols ; Selectivity ; Stationary phase ; thermodynamics ; Vapors</subject><ispartof>Analytical Sciences, 2019/06/10, Vol.35(6), pp.671-677</ispartof><rights>2019 by The Japan Society for Analytical Chemistry</rights><rights>The Japan Society for Analytical Chemistry 2019</rights><rights>Copyright Japan Science and Technology Agency 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c685t-a231ac4d0d547f8a972da77fbeae65d220922a734b1df9ddaf3f4d9e5045029d3</citedby><cites>FETCH-LOGICAL-c685t-a231ac4d0d547f8a972da77fbeae65d220922a734b1df9ddaf3f4d9e5045029d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.2116/analsci.18P537$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.2116/analsci.18P537$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,776,780,881,1877,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30773510$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/servlets/purl/1498482$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>READ, Douglas H.</creatorcontrib><creatorcontrib>ACHYUTHAN, Komandoor E.</creatorcontrib><creatorcontrib>FIX, Cory S.</creatorcontrib><creatorcontrib>MANGINELL, Ronald P.</creatorcontrib><creatorcontrib>MOORMAN, Matthew W.</creatorcontrib><creatorcontrib>SIMONSON, Robert J.</creatorcontrib><creatorcontrib>WHEELER, David R.</creatorcontrib><creatorcontrib>WHITING, Joshua J.</creatorcontrib><creatorcontrib>Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)</creatorcontrib><title>Thermodynamic Studies on a Hydrogen Bonded Acidic 3,5-Bis(trifluoromethyl)phenol-functionalized Polymer as a Gas Chromatography Stationary Phase for Selectively Speciating Chemical Warfare Agents</title><title>Analytical Sciences</title><addtitle>ANAL. SCI</addtitle><addtitle>Anal Sci</addtitle><description>We describe for the first time hydrogen bonded acid (HBA) polymer, poly{methyl[3-(2-hydroxyl, 4,6-bistrifluoromethyl)phenyl]propylsiloxane}, (DKAP), as stationary phase for gas chromatography (μGC) of organophosphate (OP), chemical warfare agent (CWA) surrogates, dimethylmethylphosphonate (DMMP), diisopropylmethylphosphonate (DIMP), diethylmethylphosphonate (DEMP), and trimethylphosphate (TMP), with high selectivity. Absorption of OPs to DKAP was one-to-several orders of magnitude higher relative to commercial polar, mid-polar, and nonpolar stationary phases. We also present for the first-time thermodynamic studies on the absorption of OP vapors and quantitative binding energy data for interactions with various stationary phases. These data help to identify the best pair of hetero-polar columns for a two-dimensional GC system, employing a nonpolar stationary phase as GC1 and DKAP as the GC2 stationary phase, for selective and rapid field detection of CWAs.</description><subject>Absorption</subject><subject>Analytical Chemistry</subject><subject>Bonding agents</subject><subject>Chemical warfare</subject><subject>Chemical warfare agents</subject><subject>Chemistry</subject><subject>Chromatography</subject><subject>DKAP</subject><subject>Gas chromatography</subject><subject>GC stationary phase</subject><subject>hydrogen bonded acid</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>Organic chemistry</subject><subject>Organophosphates</subject><subject>Phenols</subject><subject>Selectivity</subject><subject>Stationary phase</subject><subject>thermodynamics</subject><subject>Vapors</subject><issn>0910-6340</issn><issn>1348-2246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kk2LFDEQhhtR3HX16lGCXlawZ_PRn8fZUXeFBQd2xWPIJNXTGbqTMekW2r_nH7PGHkcQhFA51PO-VVRVkrxkdMEZK66UU13UdsGqdS7KR8k5E1mVcp4Vj5NzWjOaFiKjZ8mzGHeUMl5x_jQ5E7QsRc7oefLzoYXQezM51VtN7ofRWIjEO6LI7WSC34Ij194ZMGSprUFGvMvTaxsvh2CbbvTB9zC0U_d234LzXdqMTg_WY1_2B4rWvpt6CERFdLzBuGpRoQa_DWrfTlhR_abDRNatikAaH8g9dIAm36FDYA_aIuO2KAVsUnXkqwqNCkCW2N0QnydPGpwCvDj-F8mXjx8eVrfp3eebT6vlXaqLKh9SxQVTOjPU5FnZVKouuVFl2WxAQZEbzmnNuSpFtmGmqY1RjWgyU0NOs5zy2oiL5PXs6-NgJU59AN1q7xz2KllWV1nFEbqcoX3w30aIg-xt1NB1yoEfo-SsEqxirBaIvvkH3fkxHBYqcYH4RJ1lSC1mSgcfY4BG7oPtcV6SUXm4AXm8ATnfAApeHW3HTQ_mhP9ZOgJXMxAx5bYQ_tb9r-X7WbGLg9rCyVKFweoOTrjIZXEIs-yU1q0KEpz4BYoi2qw</recordid><startdate>20190610</startdate><enddate>20190610</enddate><creator>READ, Douglas H.</creator><creator>ACHYUTHAN, Komandoor E.</creator><creator>FIX, Cory S.</creator><creator>MANGINELL, Ronald P.</creator><creator>MOORMAN, Matthew W.</creator><creator>SIMONSON, Robert J.</creator><creator>WHEELER, David R.</creator><creator>WHITING, Joshua J.</creator><general>The Japan Society for Analytical Chemistry</general><general>Springer Nature Singapore</general><general>Japan Science and Technology Agency</general><general>Japan Society for Analytical Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope><scope>7X8</scope><scope>OIOZB</scope><scope>OTOTI</scope></search><sort><creationdate>20190610</creationdate><title>Thermodynamic Studies on a Hydrogen Bonded Acidic 3,5-Bis(trifluoromethyl)phenol-functionalized Polymer as a Gas Chromatography Stationary Phase for Selectively Speciating Chemical Warfare Agents</title><author>READ, Douglas H. ; ACHYUTHAN, Komandoor E. ; FIX, Cory S. ; MANGINELL, Ronald P. ; MOORMAN, Matthew W. ; SIMONSON, Robert J. ; WHEELER, David R. ; WHITING, Joshua J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c685t-a231ac4d0d547f8a972da77fbeae65d220922a734b1df9ddaf3f4d9e5045029d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Absorption</topic><topic>Analytical Chemistry</topic><topic>Bonding agents</topic><topic>Chemical warfare</topic><topic>Chemical warfare agents</topic><topic>Chemistry</topic><topic>Chromatography</topic><topic>DKAP</topic><topic>Gas chromatography</topic><topic>GC stationary phase</topic><topic>hydrogen bonded acid</topic><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>Organic chemistry</topic><topic>Organophosphates</topic><topic>Phenols</topic><topic>Selectivity</topic><topic>Stationary phase</topic><topic>thermodynamics</topic><topic>Vapors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>READ, Douglas H.</creatorcontrib><creatorcontrib>ACHYUTHAN, Komandoor E.</creatorcontrib><creatorcontrib>FIX, Cory S.</creatorcontrib><creatorcontrib>MANGINELL, Ronald P.</creatorcontrib><creatorcontrib>MOORMAN, Matthew W.</creatorcontrib><creatorcontrib>SIMONSON, Robert J.</creatorcontrib><creatorcontrib>WHEELER, David R.</creatorcontrib><creatorcontrib>WHITING, Joshua J.</creatorcontrib><creatorcontrib>Sandia National Lab. 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(SNL-NM), Albuquerque, NM (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermodynamic Studies on a Hydrogen Bonded Acidic 3,5-Bis(trifluoromethyl)phenol-functionalized Polymer as a Gas Chromatography Stationary Phase for Selectively Speciating Chemical Warfare Agents</atitle><jtitle>Analytical Sciences</jtitle><stitle>ANAL. SCI</stitle><addtitle>Anal Sci</addtitle><date>2019-06-10</date><risdate>2019</risdate><volume>35</volume><issue>6</issue><spage>671</spage><epage>677</epage><pages>671-677</pages><issn>0910-6340</issn><eissn>1348-2246</eissn><abstract>We describe for the first time hydrogen bonded acid (HBA) polymer, poly{methyl[3-(2-hydroxyl, 4,6-bistrifluoromethyl)phenyl]propylsiloxane}, (DKAP), as stationary phase for gas chromatography (μGC) of organophosphate (OP), chemical warfare agent (CWA) surrogates, dimethylmethylphosphonate (DMMP), diisopropylmethylphosphonate (DIMP), diethylmethylphosphonate (DEMP), and trimethylphosphate (TMP), with high selectivity. Absorption of OPs to DKAP was one-to-several orders of magnitude higher relative to commercial polar, mid-polar, and nonpolar stationary phases. We also present for the first-time thermodynamic studies on the absorption of OP vapors and quantitative binding energy data for interactions with various stationary phases. These data help to identify the best pair of hetero-polar columns for a two-dimensional GC system, employing a nonpolar stationary phase as GC1 and DKAP as the GC2 stationary phase, for selective and rapid field detection of CWAs.</abstract><cop>Singapore</cop><pub>The Japan Society for Analytical Chemistry</pub><pmid>30773510</pmid><doi>10.2116/analsci.18P537</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Absorption Analytical Chemistry Bonding agents Chemical warfare Chemical warfare agents Chemistry Chromatography DKAP Gas chromatography GC stationary phase hydrogen bonded acid INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Organic chemistry Organophosphates Phenols Selectivity Stationary phase thermodynamics Vapors |
| title | Thermodynamic Studies on a Hydrogen Bonded Acidic 3,5-Bis(trifluoromethyl)phenol-functionalized Polymer as a Gas Chromatography Stationary Phase for Selectively Speciating Chemical Warfare Agents |
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