Unexpected length dependence of excited-state charge transfer dynamics for surface-confined perylenediimide ensembles
The performance of devices from organic semiconductors is often governed by charge transfer phenomena at structurally and electronically complex interfaces, which remain challenging to access and study with excellent chemical and temporal resolution. Herein, we report the preparation and X-ray spect...
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| Veröffentlicht in: | Materials horizons 2017, Vol.4 (3), p.437-441 |
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| creator | Mazaheripour, Amir Kladnik, Gregor Jocson, Jonah-Micah Wardrip, Austin G. Markegard, Cade B. Frey, Nathan Cossaro, Albano Floreano, Luca Verdini, Alberto Bartlett, Andrew Burke, Anthony M. Hüsken, Nina Miller, Kelsey Van Wonterghem, Katarina Lopez, Robert Lu, Michelle Masurkar, Amrita Dickson, Mary N. Sharifzadeh, Sahar Nguyen, Hung D. Kymissis, Ioannis Cvetko, Dean Morgante, Alberto Gorodetsky, Alon A. |
| description | The performance of devices from organic semiconductors is often governed by charge transfer phenomena at structurally and electronically complex interfaces, which remain challenging to access and study with excellent chemical and temporal resolution. Herein, we report the preparation and X-ray spectroscopic characterization of well-defined model organic–inorganic interfaces. We discover an unexpected trend for our systems' associated charge transfer times, and we rationalize this trend with density functional theory calculations. Our findings hold relevance for understanding interfacial charge transfer phenomena in a variety of organic, biological, and bioinspired systems. |
| doi_str_mv | 10.1039/C6MH00465B |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 2051-6347 |
| ispartof | Materials horizons, 2017, Vol.4 (3), p.437-441 |
| issn | 2051-6347 2051-6355 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1491831 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Charge transfer Density functional theory Devices Dynamics Spectroscopy Temporal resolution Trends X rays |
| title | Unexpected length dependence of excited-state charge transfer dynamics for surface-confined perylenediimide ensembles |
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