Quantitative Evidence for Lanthanide-Oxygen Orbital Mixing in CeO2, PrO2, and TbO2

Understanding the nature of covalent (band-like) vs ionic (atomic-like) electrons in metal oxides continues to be at the forefront of research in the physical sciences. In particular, the development of a coherent and quantitative model of bonding and electronic structure for the lanthanide dioxides...

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Veröffentlicht in:Journal of the American Chemical Society 2017-12, Vol.139 (49), p.18052-18064
Hauptverfasser: Minasian, Stefan G, Batista, Enrique R, Booth, Corwin H, Clark, David L, Keith, Jason M, Kozimor, Stosh A, Lukens, Wayne W, Martin, Richard L, Shuh, David K, Stieber, S. Chantal E, Tylisczcak, Tolek, Wen, Xiao-dong
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Sprache:eng
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