Properties of perhalogenated {closo-B 10 } and {closo-B 11 } multiply charged anions and a critical comparison with {closo-B 12 } in the gas and the condensed phase

closo-Borate anions [closo-BnXn]2- are part of the most famous textbook examples of polyhedral compounds. Substantial differences in their reactivity and interactions with other compounds depending on the substituent X and cluster size n have been recognized, which favor specific closo-borates for d...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2019-03, Vol.21 (11), p.5903-5915
Hauptverfasser:	Warneke, Jonas, Konieczka, Szymon Z, Hou, Gao-Lei, Aprà, Edoardo, Kerpen, Christoph, Keppner, Fabian, Schäfer, Thomas C, Deckert, Michael, Yang, Zheng, Bylaska, Eric J, Johnson, Grant E, Laskin, Julia, Xantheas, Sotiris S, Wang, Xue-Bin, Finze, Maik
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Borates Boron Chemical synthesis Clusters Crystallography Electrochemistry Electronic structure Fragmentation Ion pairs Ions Materials science Molecular ions Molecular properties Organic chemistry Oxidation Photoelectrons Reactivity Stability Vapor phases
Online-Zugang:	Volltext
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