Light-Activated Hybrid Nanocomposite Film for Water and Oxygen Sensing
Oxygen and water vapor sensing properties are investigated in metal-oxide–hybrid polymer nanocomposite thin films generated by infiltration synthesis, which incorporates molecular ZnO into the matrix of SU-8 polymer, a common negative-tone photoresist. The hybrid thin films display 20-fold higher gr...
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| Veröffentlicht in: | ACS applied materials & interfaces 2018-09, Vol.10 (37), p.31745-31754 |
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| container_title | ACS applied materials & interfaces |
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| creator | Muckley, Eric S Collins, Liam Ievlev, Anton V Ye, Xinyi Kisslinger, Kim Sumpter, Bobby G Lavrik, Nickolay V Nam, Chang-Yong Ivanov, Ilia N |
| description | Oxygen and water vapor sensing properties are investigated in metal-oxide–hybrid polymer nanocomposite thin films generated by infiltration synthesis, which incorporates molecular ZnO into the matrix of SU-8 polymer, a common negative-tone photoresist. The hybrid thin films display 20-fold higher gravimetric responses to oxygen and water vapor than those of control ZnO thin films in the dark. An additional 50–500% enhanced responses are detected under UV irradiation. The overall enhanced gravimetric response in the hybrid film is attributed to the ZnO molecules distributed in the polymer matrix, whereas the UV enhancement is explained by the light-induced, reversible generation of hydrophilic fluoroantimonic acid from triarylsulfonium hexafluoroantimonate photoacids, which leads to the increased surface potential and adsorption energies for oxygen and water. A gravimetric sensor based on a series of ZnO-infiltrated SU-8 films under UV excitation enables 96% accurate classification of water and oxygen environment with sub 10 mTorr detection limits. The results demonstrate UV-induced fully reversible surface hydrophilicity of ZnO/SU-8 hybrid nanocomposites. |
| doi_str_mv | 10.1021/acsami.8b08072 |
| format | Article |
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The hybrid thin films display 20-fold higher gravimetric responses to oxygen and water vapor than those of control ZnO thin films in the dark. An additional 50–500% enhanced responses are detected under UV irradiation. The overall enhanced gravimetric response in the hybrid film is attributed to the ZnO molecules distributed in the polymer matrix, whereas the UV enhancement is explained by the light-induced, reversible generation of hydrophilic fluoroantimonic acid from triarylsulfonium hexafluoroantimonate photoacids, which leads to the increased surface potential and adsorption energies for oxygen and water. A gravimetric sensor based on a series of ZnO-infiltrated SU-8 films under UV excitation enables 96% accurate classification of water and oxygen environment with sub 10 mTorr detection limits. 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A gravimetric sensor based on a series of ZnO-infiltrated SU-8 films under UV excitation enables 96% accurate classification of water and oxygen environment with sub 10 mTorr detection limits. The results demonstrate UV-induced fully reversible surface hydrophilicity of ZnO/SU-8 hybrid nanocomposites.</description><subject>atomic layer deposition</subject><subject>gas sensor</subject><subject>gravimetric sensor</subject><subject>hybrid nanocomposite</subject><subject>infiltration synthesis</subject><subject>MATERIALS SCIENCE</subject><subject>QCM</subject><subject>SU-8</subject><subject>ZnO</subject><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kM9PwjAYhhujEUSvHs3iyZgMv_5gG0dCREyIHNR4bNqugxLWYrsZ-e-tGXLz9DVfnvdt-yB0jWGIgeAHoYKozbCQUEBOTlAfjxlLCzIip8czYz10EcIGIKMERueoRwFjDEXWR7OFWa2bdKIa8yUaXSbzvfSmTF6EdcrVOxdMo5OZ2dZJ5XzyERmfCFsmy-_9StvkVdtg7OoSnVViG_TVYQ7Q--zxbTpPF8un5-lkkQo6zpuU4pJhgjMmqnh_TmhZlZQUBalk3ClBR5hmY5AVpRpkJikjZQEyzyQwYBjTAbrtel1oDA8qPk6tlbNWq4ZjFv-d0QjdddDOu89Wh4bXJii93QqrXRs4gWJM8hGQLKLDDlXeheB1xXfe1MLvOQb-K5h3gvlBcAzcHLpbWevyiP8ZjcB9B8Qg37jW2-jjv7Yfv12C9A</recordid><startdate>20180919</startdate><enddate>20180919</enddate><creator>Muckley, Eric S</creator><creator>Collins, Liam</creator><creator>Ievlev, Anton V</creator><creator>Ye, Xinyi</creator><creator>Kisslinger, Kim</creator><creator>Sumpter, Bobby G</creator><creator>Lavrik, Nickolay V</creator><creator>Nam, Chang-Yong</creator><creator>Ivanov, Ilia N</creator><general>American Chemical Society</general><general>American Chemical Society (ACS)</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0001-7114-5424</orcidid><orcidid>https://orcid.org/0000-0001-6341-0355</orcidid><orcidid>https://orcid.org/0000-0002-6726-2502</orcidid><orcidid>https://orcid.org/0000-0003-3645-0508</orcidid><orcidid>https://orcid.org/0000-0002-9093-4063</orcidid><orcidid>https://orcid.org/0000000163410355</orcidid><orcidid>https://orcid.org/0000000336450508</orcidid><orcidid>https://orcid.org/0000000290934063</orcidid><orcidid>https://orcid.org/0000000267262502</orcidid><orcidid>https://orcid.org/0000000171145424</orcidid></search><sort><creationdate>20180919</creationdate><title>Light-Activated Hybrid Nanocomposite Film for Water and Oxygen Sensing</title><author>Muckley, Eric S ; Collins, Liam ; Ievlev, Anton V ; Ye, Xinyi ; Kisslinger, Kim ; Sumpter, Bobby G ; Lavrik, Nickolay V ; Nam, Chang-Yong ; Ivanov, Ilia N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a397t-31d412164af110723dfd32882fb64aca3513690bf33e0b6b342d80b76b0404113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>atomic layer deposition</topic><topic>gas sensor</topic><topic>gravimetric sensor</topic><topic>hybrid nanocomposite</topic><topic>infiltration synthesis</topic><topic>MATERIALS SCIENCE</topic><topic>QCM</topic><topic>SU-8</topic><topic>ZnO</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Muckley, Eric S</creatorcontrib><creatorcontrib>Collins, Liam</creatorcontrib><creatorcontrib>Ievlev, Anton V</creatorcontrib><creatorcontrib>Ye, Xinyi</creatorcontrib><creatorcontrib>Kisslinger, Kim</creatorcontrib><creatorcontrib>Sumpter, Bobby G</creatorcontrib><creatorcontrib>Lavrik, Nickolay V</creatorcontrib><creatorcontrib>Nam, Chang-Yong</creatorcontrib><creatorcontrib>Ivanov, Ilia N</creatorcontrib><creatorcontrib>Brookhaven National Laboratory (BNL), Upton, NY (United States)</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>ACS applied materials & interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Muckley, Eric S</au><au>Collins, Liam</au><au>Ievlev, Anton V</au><au>Ye, Xinyi</au><au>Kisslinger, Kim</au><au>Sumpter, Bobby G</au><au>Lavrik, Nickolay V</au><au>Nam, Chang-Yong</au><au>Ivanov, Ilia N</au><aucorp>Brookhaven National Laboratory (BNL), Upton, NY (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Light-Activated Hybrid Nanocomposite Film for Water and Oxygen Sensing</atitle><jtitle>ACS applied materials & interfaces</jtitle><addtitle>ACS Appl. 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| source | American Chemical Society Journals |
| subjects | atomic layer deposition gas sensor gravimetric sensor hybrid nanocomposite infiltration synthesis MATERIALS SCIENCE QCM SU-8 ZnO |
| title | Light-Activated Hybrid Nanocomposite Film for Water and Oxygen Sensing |
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