n-Heptane cool flame chemistry: Unraveling intermediate species measured in a stirred reactor and motored engine

This work identifies classes of cool flame intermediates from n-heptane low-temperature oxidation in a jet-stirred reactor (JSR) and a motored cooperative fuel research (CFR) engine. The sampled species from the JSR oxidation of a mixture of n-heptane/O2/Ar (0.01/0.11/0.88) were analyzed using a syn...

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Veröffentlicht in:	Combustion and flame 2018-01, Vol.187, p.199-216
Hauptverfasser:	Wang, Zhandong, Chen, Bingjie, Moshammer, Kai, Popolan-Vaida, Denisia M., Sioud, Salim, Shankar, Vijai Shankar Bhavani, Vuilleumier, David, Tao, Tao, Ruwe, Lena, Bräuer, Eike, Hansen, Nils, Dagaut, Philippe, Kohse-Höinghaus, Katharina, Raji, Misjudeen A., Sarathy, S. Mani
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Alkanes Alkenes APCI Orbitrap mass spectrometry Atmospheric models Auto-oxidation Chemical compounds Chemical Sciences Dienes Diketones Engineering Sciences Ethers Experiments Heptanes INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Ionization n-heptane Nuclear fuels or physical chemistry Oxidation Peroxides Photoionization Reactive fluid environment Resolution Species classification Synchrotron VUV photoionization mass spectrometry Temperature Theoretical and Ultraviolet radiation
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