Tuning of Polyoxopalladate Macroanionic Hydration Shell via Countercation Interaction

Three types of macroanion-countercation interactions in dilute solution, decided by the strength of electrostatic attraction and the change of hydration shells are reported: minor interaction between macroanions [MO8Pd12(SeO3)8]6- (M = Zn2+ or Ni2+) and monovalent cations (Na+, K+, Rb+, Cs+), leavin...

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Veröffentlicht in:	Chemistry : a European journal 2017-12, Vol.24 (12)
Hauptverfasser:	He, Jiazhi, Li, Hui, Yang, Peng, Haso, Fadi, Wu, Jiayingzi, Li, Tao, Kortz, Ulrich, Liu, Tianbo
Format:	Artikel
Sprache:	eng
Schlagworte:	hydration shell INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ion pair macroion polypalladate thermodynamics
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