Reduction of Carbonyl Groups by Uranium(III) and Formation of a Stable Amide Radical Anion

In this work, methyl benzoate, N,N-dimethylbenzamide, and benzophenone were reduced by UIII[N(SiMe3)2]3 resulting in uranium(IV) products. Reduction of benzophenone lead to UIV[OC∙Ph2)][N(SiMe3)2]3, (1.1) which forms the dinuclear complex, [N(SiMe3)2]3UIV(OCPhPh-CPh2O)UIV[N(SiMe3)2]3 (1.2), through...

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Veröffentlicht in:	Chemistry : a European journal 2017-09, Vol.24 (4)
Hauptverfasser:	Mullane, Kimberly C., Cheisson, Thibault, Nakamaru-Ogiso, Eiko, Manor, Brian C., Carroll, Patrick J., Schelter, Eric J.
Format:	Artikel
Sprache:	eng
Schlagworte:	EPR spectroscopy INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY radicals reactive intermediates redox chemistry uranium
Online-Zugang:	Volltext
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