Structure and dynamic NMR behavior of rhodium complexes supported by Lewis acidic group 13 metallatranes

Monovalent Rh was installed into the group 13 metallatranes, M[N(o-(NCH P( Pr) )C H ) ] (where M = Al and Ga, abbreviated as ML) to generate Rh → M bonds in the parent complexes, Cl-RhAlL (1-Cl) and Cl-RhGaL (2-Cl). The electron-withdrawing nature of the group 13 metalloids was probed by cyclic volt...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2017, Vol.46 (17), p.5689-5701
Hauptverfasser:	Moore, James T, Smith, Nicholas E, Lu, Connie C
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Aluminum Barriers Bimetals Bonding catalysis (heterogeneous), materials and chemistry by design, synthesis (novel materials) Exchange Gallium Phosphines
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