Role of weakly bound complexes in temperature-dependence and relative rates of MxOy− + H2O (M = Mo, W) reactions

Results of a systematic comparison of the MoxOy− + H2O and WxOy− + H2O reaction rate coefficients are reported and compared to previous experimental and computational studies on these reactions. WxOy− clusters undergo more direct oxidation by water to yield WxOy+1− + H2, while for MoxOy− clusters, p...

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Veröffentlicht in:	The Journal of chemical physics 2016-02, Vol.144 (7)
Hauptverfasser:	Kafader, Jared O, Ray, Manisha, Raghavachari Krishnan, Jarrold Caroline Chick
Format:	Artikel
Sprache:	eng
Schlagworte:	Clusters Coefficients Entrances Hydrogen production INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Lewis acid Mathematical analysis Oxidation Physics Stoichiometry Temperature Temperature dependence
Online-Zugang:	Volltext
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