[Ru(tpy)(bpy)Cl]-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects
In this work, we examine the use of competitive 13 C kinetic isotope effects ( 13 C KIEs) on CO 2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13 C KIE measurements and theoretic...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018, Vol.54 (61), p.8518-8521 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Schneider, T. W Hren, M. T Ertem, M. Z Angeles-Boza, A. M |
| description | In this work, we examine the use of competitive
13
C kinetic isotope effects (
13
C KIEs) on CO
2
reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined
13
C KIE measurements and theoretical calculations methodology for probing CO
2
conversion reactions.
13
C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO
2
reduction reaction catalyzed by a ruthenium complex. |
| doi_str_mv | 10.1039/c8cc03009j |
| format | Article |
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13
C kinetic isotope effects (
13
C KIEs) on CO
2
reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined
13
C KIE measurements and theoretical calculations methodology for probing CO
2
conversion reactions.
13
C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO
2
reduction reaction catalyzed by a ruthenium complex.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c8cc03009j</identifier><identifier>PMID: 30009305</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Carbon 13 ; Carbon dioxide ; Carbon monoxide ; Chemical reduction ; Formic acid ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; Isotopes ; Reaction mechanisms</subject><ispartof>Chemical communications (Cambridge, England), 2018, Vol.54 (61), p.8518-8521</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c400t-dda443f3b4e6621306f16888413a7dfd4bfd37146c4e4cfe5048fd94f7804fd23</citedby><cites>FETCH-LOGICAL-c400t-dda443f3b4e6621306f16888413a7dfd4bfd37146c4e4cfe5048fd94f7804fd23</cites><orcidid>0000-0002-5560-4405 ; 0000-0003-1994-9024 ; 0000000319949024 ; 0000000255604405</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,4024,27923,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30009305$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/servlets/purl/1460826$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Schneider, T. W</creatorcontrib><creatorcontrib>Hren, M. T</creatorcontrib><creatorcontrib>Ertem, M. Z</creatorcontrib><creatorcontrib>Angeles-Boza, A. M</creatorcontrib><creatorcontrib>Brookhaven National Lab. (BNL), Upton, NY (United States)</creatorcontrib><title>[Ru(tpy)(bpy)Cl]-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>In this work, we examine the use of competitive
13
C kinetic isotope effects (
13
C KIEs) on CO
2
reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined
13
C KIE measurements and theoretical calculations methodology for probing CO
2
conversion reactions.
13
C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO
2
reduction reaction catalyzed by a ruthenium complex.</description><subject>Carbon 13</subject><subject>Carbon dioxide</subject><subject>Carbon monoxide</subject><subject>Chemical reduction</subject><subject>Formic acid</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>Isotopes</subject><subject>Reaction mechanisms</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpd0d9rFDEQB_AgSltrX3yvLPpyCttONtls9lEWf1IRSguCyJJNJm3Ovc01yYLnX2-ud1YwD8lAPhkmfAl5TuGMAmvPtdQaGEC7fESOKBO8rLn89nhb123ZMF4fkqcxLiEvWssDcpgxtAzqI3L3_XJepPXm9WLIWzf-KDuV1Lj5jaYIaGadnJ8KbwutwpAr4_wvZ_Cs-IL6Vk0uJqcLN0V3c5tiMWz2rqSs-OkmvL-NPvk1Fmgt6hSfkSdWjRFP9ucxuX7_7qr7WF58_fCpe3tRag6QSmMU58yygaMQFWUgLBVSSk6Zaow1fLCGNZQLzZFrizVwaU3LbSOBW1OxY_Jy19fnGfuoXcoTaz9NeYg-vwNZiYwWO7QO_m7GmPqVixrHUU3o59hX0ICEhrU801f_0aWfw5S_sFWiautWNFm92SkdfIwBbb8ObqXCpqfQb9PqO9l192l9zvjFvuU8rNA80L_xZHC6AyHqh9t_cbM_WsmYKQ</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Schneider, T. W</creator><creator>Hren, M. T</creator><creator>Ertem, M. Z</creator><creator>Angeles-Boza, A. M</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-5560-4405</orcidid><orcidid>https://orcid.org/0000-0003-1994-9024</orcidid><orcidid>https://orcid.org/0000000319949024</orcidid><orcidid>https://orcid.org/0000000255604405</orcidid></search><sort><creationdate>2018</creationdate><title>[Ru(tpy)(bpy)Cl]-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects</title><author>Schneider, T. W ; Hren, M. T ; Ertem, M. Z ; Angeles-Boza, A. M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c400t-dda443f3b4e6621306f16888413a7dfd4bfd37146c4e4cfe5048fd94f7804fd23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Carbon 13</topic><topic>Carbon dioxide</topic><topic>Carbon monoxide</topic><topic>Chemical reduction</topic><topic>Formic acid</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Isotopes</topic><topic>Reaction mechanisms</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schneider, T. W</creatorcontrib><creatorcontrib>Hren, M. T</creatorcontrib><creatorcontrib>Ertem, M. Z</creatorcontrib><creatorcontrib>Angeles-Boza, A. M</creatorcontrib><creatorcontrib>Brookhaven National Lab. (BNL), Upton, NY (United States)</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schneider, T. W</au><au>Hren, M. T</au><au>Ertem, M. Z</au><au>Angeles-Boza, A. M</au><aucorp>Brookhaven National Lab. (BNL), Upton, NY (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>[Ru(tpy)(bpy)Cl]-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2018</date><risdate>2018</risdate><volume>54</volume><issue>61</issue><spage>8518</spage><epage>8521</epage><pages>8518-8521</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>In this work, we examine the use of competitive
13
C kinetic isotope effects (
13
C KIEs) on CO
2
reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined
13
C KIE measurements and theoretical calculations methodology for probing CO
2
conversion reactions.
13
C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO
2
reduction reaction catalyzed by a ruthenium complex.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30009305</pmid><doi>10.1039/c8cc03009j</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-5560-4405</orcidid><orcidid>https://orcid.org/0000-0003-1994-9024</orcidid><orcidid>https://orcid.org/0000000319949024</orcidid><orcidid>https://orcid.org/0000000255604405</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2018, Vol.54 (61), p.8518-8521 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_osti_scitechconnect_1460826 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Carbon 13 Carbon dioxide Carbon monoxide Chemical reduction Formic acid INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Isotopes Reaction mechanisms |
| title | [Ru(tpy)(bpy)Cl]-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects |
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