[Ru II (tpy)(bpy)Cl] + -Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

[Ru II (tpy)(bpy)Cl] + -Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

In this work, we examine the use of competitive 13C kinetic isotope effects (13C KIEs) on CO2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13C KIE measurements and theoretical ca...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (61), p.8518-8521
Hauptverfasser: Schneider, T W, Hren, M T, Ertem, M Z, Angeles-Boza, A M
Format: Artikel
Sprache:eng
Schlagworte:
Carbon 13
Carbon dioxide
Carbon monoxide
Chemical reduction
Formic acid
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Isotopes
Reaction mechanisms
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In this work, we examine the use of competitive 13C kinetic isotope effects (13C KIEs) on CO2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13C KIE measurements and theoretical calculations methodology for probing CO2 conversion reactions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc03009j