Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries

A silicon-graphite blended anode is paired with a high capacity LiFePO4 reference/counter electrode to track irreversibility and lithium inventory. The LiFePO4 electrode provides a reliable, flat potential for dQ dV-1 analysis of LixSi and LixC electrochemical reactions. We relate this electrochemis...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (29), p.3586-3589
Hauptverfasser: Dose, W M, Piernas-Muñoz, M J, Maroni, V A, Trask, S E, Bloom, I, Johnson, C S
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container_end_page 3589
container_issue 29
container_start_page 3586
container_title Chemical communications (Cambridge, England)
container_volume 54
creator Dose, W M
Piernas-Muñoz, M J
Maroni, V A
Trask, S E
Bloom, I
Johnson, C S
description A silicon-graphite blended anode is paired with a high capacity LiFePO4 reference/counter electrode to track irreversibility and lithium inventory. The LiFePO4 electrode provides a reliable, flat potential for dQ dV-1 analysis of LixSi and LixC electrochemical reactions. We relate this electrochemistry to the morphological and physical changes taking place.
doi_str_mv 10.1039/c8cc00456k
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source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Chemical reactions
Electrochemistry
Electrodes
ENERGY STORAGE
Graphite
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Lithium
Lithium-ion batteries
MATERIALS SCIENCE
Rechargeable batteries
Silicon
title Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries
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