Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries
A silicon-graphite blended anode is paired with a high capacity LiFePO4 reference/counter electrode to track irreversibility and lithium inventory. The LiFePO4 electrode provides a reliable, flat potential for dQ dV-1 analysis of LixSi and LixC electrochemical reactions. We relate this electrochemis...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018, Vol.54 (29), p.3586-3589 |
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creator | Dose, W M Piernas-Muñoz, M J Maroni, V A Trask, S E Bloom, I Johnson, C S |
description | A silicon-graphite blended anode is paired with a high capacity LiFePO4 reference/counter electrode to track irreversibility and lithium inventory. The LiFePO4 electrode provides a reliable, flat potential for dQ dV-1 analysis of LixSi and LixC electrochemical reactions. We relate this electrochemistry to the morphological and physical changes taking place. |
doi_str_mv | 10.1039/c8cc00456k |
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subjects | Chemical reactions Electrochemistry Electrodes ENERGY STORAGE Graphite INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Lithium Lithium-ion batteries MATERIALS SCIENCE Rechargeable batteries Silicon |
title | Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries |
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