Formal Nickelate(−I) Complexes Supported by Group 13 Ions

Formal nickelate(−I) complexes bearing Group 13 metalloligands (M=Al and Ga) were isolated. These 17 e− complexes were synthesized by one‐electron reduction of the corresponding Ni0→MIII precursors, and were investigated by single‐crystal X‐ray diffraction, EPR spectroscopy, and quantum chemical cal...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2018-06, Vol.57 (26), p.7815-7819
Hauptverfasser:	Vollmer, Matthew V., Xie, Jing, Cammarota, Ryan C., Young, Victor G., Bill, Eckhard, Gagliardi, Laura, Lu, Connie C.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Chemical bonds Computer applications EPR spectroscopy Gallium Group 13 elements metalates Molecular chains Molecular orbitals Nickel Organic chemistry Quantum chemistry radicals Reduction Spectroscopy X-ray diffraction
Online-Zugang:	Volltext
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