Controlled Expansion of a Strong‐Field Iron Nitride Cluster: Multi‐Site Ligand Substitution as a Strategy for Activating Interstitial Nitride Nucleophilicity

Multimetallic clusters have long been investigated as molecular surrogates for reactive sites on metal surfaces. In the case of the μ4‐nitrido cluster [Fe4(μ4‐N)(CO)12]−, this analogy is limited owing to the electron‐withdrawing effect of carbonyl ligands on the iron nitride core. Described here is...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2018-10, Vol.57 (40), p.13057-13061
Hauptverfasser:	Drance, Myles J., Mokhtarzadeh, Charles C., Melaimi, Mohand, Agnew, Douglas W., Moore, Curtis E., Rheingold, Arnold L., Figueroa, Joshua S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyls cluster expansion Clusters Iron Iron nitride isocyanides Ligands metal clusters Metal surfaces Metals nitrides
Online-Zugang:	Volltext
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