Investigation of Oxygen Reduction Activity of Catalysts Derived from Co and Co/Zn Methyl-Imidazolate Frameworks in Proton Exchange Membrane Fuel Cells
We demonstrated that the oxygen reduction reaction (ORR) activity over the catalysts derived from pyrolyzed cobalt zeolitic imidazolate frameworks depends strongly on the imidazole ligand structure and cobalt content. The activity and durability of these catalysts were tested in the proton exchange...
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| Veröffentlicht in: | ChemElectroChem 2016-05, Vol.3 (10) |
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| creator | Chong, Lina Goenaga, Gabriel A. Williams, Kia Barkholtz, Heather M. Grabstanowicz, Lauren R. Brooksbank, Jeremy A. Papandrew, Alex B. Elzein, Radwan Schlaf, Rudiger Zawodzinski, Thomas A. Zou, Jianxin Ma, Shengqian Liu, Di-Jia |
| description | We demonstrated that the oxygen reduction reaction (ORR) activity over the catalysts derived from pyrolyzed cobalt zeolitic imidazolate frameworks depends strongly on the imidazole ligand structure and cobalt content. The activity and durability of these catalysts were tested in the proton exchange membrane fuel cell for the first time. The membrane electrode assembly containing a catalyst derived from Co/Zn bimetallic ZIF at cathode achieved an open circuit voltage of 0.93 V, a current density of 28 mA cm-2 at 0.8 ViR-free and a peak power density of 374 mW cm-2. |
| doi_str_mv | 10.1002/celc.201600163 |
| format | Article |
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(ANL), Argonne, IL (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of Oxygen Reduction Activity of Catalysts Derived from Co and Co/Zn Methyl-Imidazolate Frameworks in Proton Exchange Membrane Fuel Cells</atitle><jtitle>ChemElectroChem</jtitle><date>2016-05-31</date><risdate>2016</risdate><volume>3</volume><issue>10</issue><issn>2196-0216</issn><eissn>2196-0216</eissn><abstract>We demonstrated that the oxygen reduction reaction (ORR) activity over the catalysts derived from pyrolyzed cobalt zeolitic imidazolate frameworks depends strongly on the imidazole ligand structure and cobalt content. The activity and durability of these catalysts were tested in the proton exchange membrane fuel cell for the first time. 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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | electrocatalysts fuel cell metal-organic frameworks oxygen reduction reaction |
| title | Investigation of Oxygen Reduction Activity of Catalysts Derived from Co and Co/Zn Methyl-Imidazolate Frameworks in Proton Exchange Membrane Fuel Cells |
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