In situ X-ray diffraction analysis of (CFx)n batteries: signal extraction by multivariate analysis
(CFx)n cathode reaction during discharge has been investigated using in situ X‐ray diffraction (XRD). Mathematical treatment of the in situ XRD data set was performed using multivariate curve resolution with alternating least squares (MCR–ALS), a technique of multivariate analysis. MCR–ALS analysis...
Gespeichert in:
| Veröffentlicht in: | Journal of applied crystallography 2007-12, Vol.40 (6), p.1097-1104 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1104 |
|---|---|
| container_issue | 6 |
| container_start_page | 1097 |
| container_title | Journal of applied crystallography |
| container_volume | 40 |
| creator | Rodriguez, Mark A. Keenan, Michael R. Nagasubramanian, Ganesan |
| description | (CFx)n cathode reaction during discharge has been investigated using in situ X‐ray diffraction (XRD). Mathematical treatment of the in situ XRD data set was performed using multivariate curve resolution with alternating least squares (MCR–ALS), a technique of multivariate analysis. MCR–ALS analysis successfully separated the relatively weak XRD signal intensity due to the chemical reaction from the other inert cell component signals. The resulting dynamic reaction component revealed the loss of (CFx)n cathode signal together with the simultaneous appearance of LiF by‐product intensity. Careful examination of the XRD data set revealed an additional dynamic component which may be associated with the formation of an intermediate compound during the discharge process. |
| doi_str_mv | 10.1107/S0021889807042045 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_1426963</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>31833874</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3323-6cc517fc98f5303e90e8de1eedaa52f1e2d8044bcf0380d141f0adb9a1bb6a1d3</originalsourceid><addsrcrecordid>eNqFkcFu1DAQhiMEEqXwANwsDggOKTNx7Djc2oUtXVUgoAjExXKcMbhkk2I7dPP2pAosSBw4zUjzfb9mNFn2EOEIEapn7wEKVKpWUEFZQCluZQcoAXJRyer2X_3d7F6MlwAoq6I4yJqznkWfRvYpD2ZirXcuGJv80DPTm26KPrLBsSer9e5pzxqTEgVP8fksfZnnjHbpN99MbDt2yf8wwZtEe_9-dseZLtKDX_Uw-7B-ebF6lZ-_OT1bHZ_nlvOC59JagZWztXKCA6caSLWERK0xonBIRaugLBvrgCtosUQHpm1qg00jDbb8MHu05A4xeR2tT2S_2qHvySaNZSFryWfo8QJdheH7SDHprY-Wus70NIxRc1Scq6r8k7YHL4cxzCdFXYBAEEriDOEC2TDEGMjpq-C3JkwaQd_8Rf_zl9lRi3PtO5r-L-jN6t3xRoC6WT5fVB8T7faqCd-0rHgl9MfXp_rzxVvYnKxf6JL_BMcKnx4</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>205105861</pqid></control><display><type>article</type><title>In situ X-ray diffraction analysis of (CFx)n batteries: signal extraction by multivariate analysis</title><source>Wiley Online Library Journals Frontfile Complete</source><source>Alma/SFX Local Collection</source><creator>Rodriguez, Mark A. ; Keenan, Michael R. ; Nagasubramanian, Ganesan</creator><creatorcontrib>Rodriguez, Mark A. ; Keenan, Michael R. ; Nagasubramanian, Ganesan ; Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)</creatorcontrib><description>(CFx)n cathode reaction during discharge has been investigated using in situ X‐ray diffraction (XRD). Mathematical treatment of the in situ XRD data set was performed using multivariate curve resolution with alternating least squares (MCR–ALS), a technique of multivariate analysis. MCR–ALS analysis successfully separated the relatively weak XRD signal intensity due to the chemical reaction from the other inert cell component signals. The resulting dynamic reaction component revealed the loss of (CFx)n cathode signal together with the simultaneous appearance of LiF by‐product intensity. Careful examination of the XRD data set revealed an additional dynamic component which may be associated with the formation of an intermediate compound during the discharge process.</description><identifier>ISSN: 1600-5767</identifier><identifier>ISSN: 0021-8898</identifier><identifier>EISSN: 1600-5767</identifier><identifier>DOI: 10.1107/S0021889807042045</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: Blackwell Publishing Ltd</publisher><subject>Batteries ; Crystallography ; Diffraction ; dynamic reaction behaviour ; ENERGY STORAGE ; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY ; MATERIALS SCIENCE ; multivariate analysis ; Statistical analysis ; weak diffraction signals ; X-rays</subject><ispartof>Journal of applied crystallography, 2007-12, Vol.40 (6), p.1097-1104</ispartof><rights>International Union of Crystallography, 2007</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3323-6cc517fc98f5303e90e8de1eedaa52f1e2d8044bcf0380d141f0adb9a1bb6a1d3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1107%2FS0021889807042045$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1107%2FS0021889807042045$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,776,780,881,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.osti.gov/servlets/purl/1426963$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Rodriguez, Mark A.</creatorcontrib><creatorcontrib>Keenan, Michael R.</creatorcontrib><creatorcontrib>Nagasubramanian, Ganesan</creatorcontrib><creatorcontrib>Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)</creatorcontrib><title>In situ X-ray diffraction analysis of (CFx)n batteries: signal extraction by multivariate analysis</title><title>Journal of applied crystallography</title><addtitle>J. Appl. Cryst</addtitle><description>(CFx)n cathode reaction during discharge has been investigated using in situ X‐ray diffraction (XRD). Mathematical treatment of the in situ XRD data set was performed using multivariate curve resolution with alternating least squares (MCR–ALS), a technique of multivariate analysis. MCR–ALS analysis successfully separated the relatively weak XRD signal intensity due to the chemical reaction from the other inert cell component signals. The resulting dynamic reaction component revealed the loss of (CFx)n cathode signal together with the simultaneous appearance of LiF by‐product intensity. Careful examination of the XRD data set revealed an additional dynamic component which may be associated with the formation of an intermediate compound during the discharge process.</description><subject>Batteries</subject><subject>Crystallography</subject><subject>Diffraction</subject><subject>dynamic reaction behaviour</subject><subject>ENERGY STORAGE</subject><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><subject>MATERIALS SCIENCE</subject><subject>multivariate analysis</subject><subject>Statistical analysis</subject><subject>weak diffraction signals</subject><subject>X-rays</subject><issn>1600-5767</issn><issn>0021-8898</issn><issn>1600-5767</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqFkcFu1DAQhiMEEqXwANwsDggOKTNx7Djc2oUtXVUgoAjExXKcMbhkk2I7dPP2pAosSBw4zUjzfb9mNFn2EOEIEapn7wEKVKpWUEFZQCluZQcoAXJRyer2X_3d7F6MlwAoq6I4yJqznkWfRvYpD2ZirXcuGJv80DPTm26KPrLBsSer9e5pzxqTEgVP8fksfZnnjHbpN99MbDt2yf8wwZtEe_9-dseZLtKDX_Uw-7B-ebF6lZ-_OT1bHZ_nlvOC59JagZWztXKCA6caSLWERK0xonBIRaugLBvrgCtosUQHpm1qg00jDbb8MHu05A4xeR2tT2S_2qHvySaNZSFryWfo8QJdheH7SDHprY-Wus70NIxRc1Scq6r8k7YHL4cxzCdFXYBAEEriDOEC2TDEGMjpq-C3JkwaQd_8Rf_zl9lRi3PtO5r-L-jN6t3xRoC6WT5fVB8T7faqCd-0rHgl9MfXp_rzxVvYnKxf6JL_BMcKnx4</recordid><startdate>200712</startdate><enddate>200712</enddate><creator>Rodriguez, Mark A.</creator><creator>Keenan, Michael R.</creator><creator>Nagasubramanian, Ganesan</creator><general>Blackwell Publishing Ltd</general><general>International Union of Crystallography</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>OIOZB</scope><scope>OTOTI</scope></search><sort><creationdate>200712</creationdate><title>In situ X-ray diffraction analysis of (CFx)n batteries: signal extraction by multivariate analysis</title><author>Rodriguez, Mark A. ; Keenan, Michael R. ; Nagasubramanian, Ganesan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3323-6cc517fc98f5303e90e8de1eedaa52f1e2d8044bcf0380d141f0adb9a1bb6a1d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Batteries</topic><topic>Crystallography</topic><topic>Diffraction</topic><topic>dynamic reaction behaviour</topic><topic>ENERGY STORAGE</topic><topic>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</topic><topic>MATERIALS SCIENCE</topic><topic>multivariate analysis</topic><topic>Statistical analysis</topic><topic>weak diffraction signals</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rodriguez, Mark A.</creatorcontrib><creatorcontrib>Keenan, Michael R.</creatorcontrib><creatorcontrib>Nagasubramanian, Ganesan</creatorcontrib><creatorcontrib>Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Journal of applied crystallography</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rodriguez, Mark A.</au><au>Keenan, Michael R.</au><au>Nagasubramanian, Ganesan</au><aucorp>Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In situ X-ray diffraction analysis of (CFx)n batteries: signal extraction by multivariate analysis</atitle><jtitle>Journal of applied crystallography</jtitle><addtitle>J. Appl. Cryst</addtitle><date>2007-12</date><risdate>2007</risdate><volume>40</volume><issue>6</issue><spage>1097</spage><epage>1104</epage><pages>1097-1104</pages><issn>1600-5767</issn><issn>0021-8898</issn><eissn>1600-5767</eissn><abstract>(CFx)n cathode reaction during discharge has been investigated using in situ X‐ray diffraction (XRD). Mathematical treatment of the in situ XRD data set was performed using multivariate curve resolution with alternating least squares (MCR–ALS), a technique of multivariate analysis. MCR–ALS analysis successfully separated the relatively weak XRD signal intensity due to the chemical reaction from the other inert cell component signals. The resulting dynamic reaction component revealed the loss of (CFx)n cathode signal together with the simultaneous appearance of LiF by‐product intensity. Careful examination of the XRD data set revealed an additional dynamic component which may be associated with the formation of an intermediate compound during the discharge process.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1107/S0021889807042045</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1600-5767 |
| ispartof | Journal of applied crystallography, 2007-12, Vol.40 (6), p.1097-1104 |
| issn | 1600-5767 0021-8898 1600-5767 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1426963 |
| source | Wiley Online Library Journals Frontfile Complete; Alma/SFX Local Collection |
| subjects | Batteries Crystallography Diffraction dynamic reaction behaviour ENERGY STORAGE INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY MATERIALS SCIENCE multivariate analysis Statistical analysis weak diffraction signals X-rays |
| title | In situ X-ray diffraction analysis of (CFx)n batteries: signal extraction by multivariate analysis |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-06T13%3A56%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=In%20situ%20X-ray%20diffraction%20analysis%20of%20(CFx)n%20batteries:%20signal%20extraction%20by%20multivariate%20analysis&rft.jtitle=Journal%20of%20applied%20crystallography&rft.au=Rodriguez,%20Mark%20A.&rft.aucorp=Sandia%20National%20Lab.%20(SNL-NM),%20Albuquerque,%20NM%20(United%20States)&rft.date=2007-12&rft.volume=40&rft.issue=6&rft.spage=1097&rft.epage=1104&rft.pages=1097-1104&rft.issn=1600-5767&rft.eissn=1600-5767&rft_id=info:doi/10.1107/S0021889807042045&rft_dat=%3Cproquest_osti_%3E31833874%3C/proquest_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=205105861&rft_id=info:pmid/&rfr_iscdi=true |