Influence of lanthanides on spin-relaxation and spin-structure in a family of Fe7Ln4 single molecule magnets

A family of isostructural undecanuclear 3d–4f coordination clusters of formula [Fe7IIILn4IIIO4(OH)3(tea)2(Htea)3(Piv)7(H2O)2(NO3)3], where Ln = Y (1), Gd (2), Tb (3), Dy (4); PivH ≡ pivalic acid and H3tea ≡ triethanolamine, was synthesised. The central Fe7 core of the coordination cluster can be des...

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Veröffentlicht in:	Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2018, Vol.6 (11), p.2862-2872
Hauptverfasser:	Prodius, Denis, Mereacre, Valeriu, Singh, Prashant, Lan, Yanhua, Mameri, Samir, Johnson, Duane D, Wernsdorfer, Wolfgang, Anson, Christopher E, Powell, Annie K
Format:	Artikel
Sprache:	eng
Schlagworte:	Dihedral angle Dysprosium Gadolinium INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Iron Iron 57 Lanthanides Magnets Rare earth elements Spectra Superconducting quantum interference devices Temperature dependence Triethanolamine Variation
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