Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform
The crystal structures of americium species containing a common multifunctional phosphine oxide ligand, reported for its ability to extract f elements from acidic solutions, namely, 2,6-[Ph2P(O)CH2]2C5H3–NO, L, were finally determined after over three decades of separations studies involving these...
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| Veröffentlicht in: | Inorganic chemistry 2018-02, Vol.57 (4), p.2278-2287 |
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| container_title | Inorganic chemistry |
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| creator | Corbey, Jordan F Rapko, Brian M Wang, Zheming McNamara, Bruce K Surbella, Robert G Pellegrini, Kristi L Schwantes, Jon M |
| description | The crystal structures of americium species containing a common multifunctional phosphine oxide ligand, reported for its ability to extract f elements from acidic solutions, namely, 2,6-[Ph2P(O)CH2]2C5H3–NO, L, were finally determined after over three decades of separations studies involving these species and their surrogates. The molecular compounds Am(L)(NO3)3, Am 1:1, and [Am(L)2(NO3)][2(NO3)], Am 2:1, along with their neodymium and europium analogues, were synthesized and characterized using single-crystal X-ray crystallography, attenuated total reflectance Fourier transform infrared spectroscopy, and luminescence spectroscopy to provide a comprehensive comparison with new and known analogous complexes. |
| doi_str_mv | 10.1021/acs.inorgchem.7b03154 |
| format | Article |
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The molecular compounds Am(L)(NO3)3, Am 1:1, and [Am(L)2(NO3)][2(NO3)], Am 2:1, along with their neodymium and europium analogues, were synthesized and characterized using single-crystal X-ray crystallography, attenuated total reflectance Fourier transform infrared spectroscopy, and luminescence spectroscopy to provide a comprehensive comparison with new and known analogous complexes.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.7b03154</identifier><identifier>PMID: 29406706</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform ; Environmental Molecular Sciences Laboratory</subject><ispartof>Inorganic chemistry, 2018-02, Vol.57 (4), p.2278-2287</ispartof><rights>Copyright © 2018 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a378t-5bc43bfdf9ce0c2236c37cd55e34477e918a2da2bee2daadbac3a66bb410b9323</citedby><cites>FETCH-LOGICAL-a378t-5bc43bfdf9ce0c2236c37cd55e34477e918a2da2bee2daadbac3a66bb410b9323</cites><orcidid>0000-0002-3273-3044 ; 0000000232733044</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.7b03154$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.inorgchem.7b03154$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,776,780,881,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29406706$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/1423404$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Corbey, Jordan F</creatorcontrib><creatorcontrib>Rapko, Brian M</creatorcontrib><creatorcontrib>Wang, Zheming</creatorcontrib><creatorcontrib>McNamara, Bruce K</creatorcontrib><creatorcontrib>Surbella, Robert G</creatorcontrib><creatorcontrib>Pellegrini, Kristi L</creatorcontrib><creatorcontrib>Schwantes, Jon M</creatorcontrib><creatorcontrib>Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)</creatorcontrib><title>Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform</title><title>Inorganic chemistry</title><addtitle>Inorg. 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The molecular compounds Am(L)(NO3)3, Am 1:1, and [Am(L)2(NO3)][2(NO3)], Am 2:1, along with their neodymium and europium analogues, were synthesized and characterized using single-crystal X-ray crystallography, attenuated total reflectance Fourier transform infrared spectroscopy, and luminescence spectroscopy to provide a comprehensive comparison with new and known analogous complexes.</description><subject>Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform</subject><subject>Environmental Molecular Sciences Laboratory</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFUVuL1DAUDqK44-pPUIpPsw8dc2u7eVyLNxjcBRUEkZCmp9MsTdJNUtjxn_hvzTjjvkoezjnhu8D3IfSS4A3BlLxROm6M82GnR7CbpsOMVPwRWpGK4rIi-PtjtMI476SuxRl6FuMtxlgwXj9FZ1RwXDe4XqHfbdjHpKbJ74KaR6ML5friyww6BR-1n_NPO6qgdIJgfqlkvCv8UFzZfGqz2KL1dp7gHmLeXFLGGbcr0gjFWxN_rOfRxyzr_IWFNO6nn_M-mN44KEnp700Pxfrz9U1-F8XW7A7eN5NKgw_2OXoyqCnCi9M8R9_ev_vafiy31x8-tVfbUrHmMpVVpznrhn4QGrCmlNWaNbqvKmCcNw0Icqlor2gHkIfqO6WZquuu4wR3glF2jl4fdX1MRkZtEuhRe-dyBJJwyjjmGbQ-gubg7xaISVoTNUyTcuCXKIkQgmSrv3rVEapzgDHAIOdgrAp7SbA8VCdzdfKhOnmqLvNenSyWzkL_wPrXVQaQI-DAv_VLcDmW_4j-AY6MrXQ</recordid><startdate>20180219</startdate><enddate>20180219</enddate><creator>Corbey, Jordan F</creator><creator>Rapko, Brian M</creator><creator>Wang, Zheming</creator><creator>McNamara, Bruce K</creator><creator>Surbella, Robert G</creator><creator>Pellegrini, Kristi L</creator><creator>Schwantes, Jon M</creator><general>American Chemical Society</general><general>American Chemical Society (ACS)</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-3273-3044</orcidid><orcidid>https://orcid.org/0000000232733044</orcidid></search><sort><creationdate>20180219</creationdate><title>Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform</title><author>Corbey, Jordan F ; Rapko, Brian M ; Wang, Zheming ; McNamara, Bruce K ; Surbella, Robert G ; Pellegrini, Kristi L ; Schwantes, Jon M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a378t-5bc43bfdf9ce0c2236c37cd55e34477e918a2da2bee2daadbac3a66bb410b9323</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform</topic><topic>Environmental Molecular Sciences Laboratory</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Corbey, Jordan F</creatorcontrib><creatorcontrib>Rapko, Brian M</creatorcontrib><creatorcontrib>Wang, Zheming</creatorcontrib><creatorcontrib>McNamara, Bruce K</creatorcontrib><creatorcontrib>Surbella, Robert G</creatorcontrib><creatorcontrib>Pellegrini, Kristi L</creatorcontrib><creatorcontrib>Schwantes, Jon M</creatorcontrib><creatorcontrib>Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Corbey, Jordan F</au><au>Rapko, Brian M</au><au>Wang, Zheming</au><au>McNamara, Bruce K</au><au>Surbella, Robert G</au><au>Pellegrini, Kristi L</au><au>Schwantes, Jon M</au><aucorp>Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2018-02-19</date><risdate>2018</risdate><volume>57</volume><issue>4</issue><spage>2278</spage><epage>2287</epage><pages>2278-2287</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>The crystal structures of americium species containing a common multifunctional phosphine oxide ligand, reported for its ability to extract f elements from acidic solutions, namely, 2,6-[Ph2P(O)CH2]2C5H3–NO, L, were finally determined after over three decades of separations studies involving these species and their surrogates. The molecular compounds Am(L)(NO3)3, Am 1:1, and [Am(L)2(NO3)][2(NO3)], Am 2:1, along with their neodymium and europium analogues, were synthesized and characterized using single-crystal X-ray crystallography, attenuated total reflectance Fourier transform infrared spectroscopy, and luminescence spectroscopy to provide a comprehensive comparison with new and known analogous complexes.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>29406706</pmid><doi>10.1021/acs.inorgchem.7b03154</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-3273-3044</orcidid><orcidid>https://orcid.org/0000000232733044</orcidid></addata></record> |
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| subjects | Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform Environmental Molecular Sciences Laboratory |
| title | Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform |
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