Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries
A fluorine‐doped antiperovskite Li‐ion conductor Li2(OH)X (X=Cl, Br) is shown to be a promising candidate for a solid electrolyte in an all‐solid‐state Li‐ion rechargeable battery. Substitution of F− for OH− transforms orthorhombic Li2OHCl to a room‐temperature cubic phase, which shows electrochemic...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie (International ed.) 2016-08, Vol.55 (34), p.9965-9968 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 9968 |
|---|---|
| container_issue | 34 |
| container_start_page | 9965 |
| container_title | Angewandte Chemie (International ed.) |
| container_volume | 55 |
| creator | Li, Yutao Zhou, Weidong Xin, Sen Li, Shuai Zhu, Jinlong Lü, Xujie Cui, Zhiming Jia, Quanxi Zhou, Jianshi Zhao, Yusheng Goodenough, John B. |
| description | A fluorine‐doped antiperovskite Li‐ion conductor Li2(OH)X (X=Cl, Br) is shown to be a promising candidate for a solid electrolyte in an all‐solid‐state Li‐ion rechargeable battery. Substitution of F− for OH− transforms orthorhombic Li2OHCl to a room‐temperature cubic phase, which shows electrochemical stability to 9 V versus Li+/Li and two orders of magnitude higher Li‐ion conductivity than that of orthorhombic Li2OHCl. An all‐solid‐state Li/LiFePO4 with F‐doped Li2OHCl as the solid electrolyte showed good cyclability and a high coulombic efficiency over 40 charge/discharge cycles.
Higher conductivity: A fluorine‐doped antiperovskite Li‐ion conductor Li2(OH)0.9F0.1Cl shows electrochemical stability up to 9 V versus Li+/Li and two orders of magnitude higher Li‐ion conductivity than that of orthorhombic Li2OHCl. |
| doi_str_mv | 10.1002/anie.201604554 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_1414136</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>4148173761</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5814-21c0861b874e773590ed7398a6cac867cddd670c5943c1b82edd076595a722cf3</originalsourceid><addsrcrecordid>eNqFkc1vEzEUxC0EoqVw5YgiuHBx8Mfa3j2GkoaIqCBS4Gi59ovq1lkH2wvkv8fRlghxQT74yfrNaPwGoeeUTCkh7I3pPUwZoZI0QjQP0CkVjGKuFH9Y54ZzrFpBT9CTnG8r37ZEPkYnTHEhO8FP0foiDDH5HvC7uAM3mfXF7yDFH_nOF5jMA9iSYtjXeRPTZBYCXsfgHV4XU99Wvtz4YYuXsZ-8NaVA8pCfokcbEzI8u7_P0JeL-dX5e7z6uFiez1bYipY2mFFLWkmvW9VAzSs6Ak7xrjXSGttKZZ1zUhEruobbijFwjigpOmEUY3bDz9DL0Tfm4nW2NbC9sbHva2ZNm3q4rNDrEdql-H2AXPTWZwshmB7ikDVtKRGyrqap6Kt_0Ns4pL5-4UDRut-apFLTkbIp5pxgo3fJb03aa0r0oRN96EQfO6mCF_e2w_UW3BH_U0IFuhH46QPs_2OnZ5fL-d_meNT6XODXUWvSnZaKK6G_XS70gl99lh--Mv2J_wYzBaWi</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1811554943</pqid></control><display><type>article</type><title>Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Li, Yutao ; Zhou, Weidong ; Xin, Sen ; Li, Shuai ; Zhu, Jinlong ; Lü, Xujie ; Cui, Zhiming ; Jia, Quanxi ; Zhou, Jianshi ; Zhao, Yusheng ; Goodenough, John B.</creator><creatorcontrib>Li, Yutao ; Zhou, Weidong ; Xin, Sen ; Li, Shuai ; Zhu, Jinlong ; Lü, Xujie ; Cui, Zhiming ; Jia, Quanxi ; Zhou, Jianshi ; Zhao, Yusheng ; Goodenough, John B. ; Univ. of Nevada, Las Vegas, NV (United States) ; Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)</creatorcontrib><description>A fluorine‐doped antiperovskite Li‐ion conductor Li2(OH)X (X=Cl, Br) is shown to be a promising candidate for a solid electrolyte in an all‐solid‐state Li‐ion rechargeable battery. Substitution of F− for OH− transforms orthorhombic Li2OHCl to a room‐temperature cubic phase, which shows electrochemical stability to 9 V versus Li+/Li and two orders of magnitude higher Li‐ion conductivity than that of orthorhombic Li2OHCl. An all‐solid‐state Li/LiFePO4 with F‐doped Li2OHCl as the solid electrolyte showed good cyclability and a high coulombic efficiency over 40 charge/discharge cycles.
Higher conductivity: A fluorine‐doped antiperovskite Li‐ion conductor Li2(OH)0.9F0.1Cl shows electrochemical stability up to 9 V versus Li+/Li and two orders of magnitude higher Li‐ion conductivity than that of orthorhombic Li2OHCl.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201604554</identifier><identifier>PMID: 27356953</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>all-solid-state battery ; antiperovskite ; Electrolytes ; Energy Sciences ; ENERGY STORAGE ; Lithium ; lithium-ion battery ; solid electrolyte</subject><ispartof>Angewandte Chemie (International ed.), 2016-08, Vol.55 (34), p.9965-9968</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5814-21c0861b874e773590ed7398a6cac867cddd670c5943c1b82edd076595a722cf3</citedby><cites>FETCH-LOGICAL-c5814-21c0861b874e773590ed7398a6cac867cddd670c5943c1b82edd076595a722cf3</cites><orcidid>0000000311716437 ; 0000000184027160</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201604554$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201604554$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,776,780,881,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27356953$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/servlets/purl/1414136$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Yutao</creatorcontrib><creatorcontrib>Zhou, Weidong</creatorcontrib><creatorcontrib>Xin, Sen</creatorcontrib><creatorcontrib>Li, Shuai</creatorcontrib><creatorcontrib>Zhu, Jinlong</creatorcontrib><creatorcontrib>Lü, Xujie</creatorcontrib><creatorcontrib>Cui, Zhiming</creatorcontrib><creatorcontrib>Jia, Quanxi</creatorcontrib><creatorcontrib>Zhou, Jianshi</creatorcontrib><creatorcontrib>Zhao, Yusheng</creatorcontrib><creatorcontrib>Goodenough, John B.</creatorcontrib><creatorcontrib>Univ. of Nevada, Las Vegas, NV (United States)</creatorcontrib><creatorcontrib>Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)</creatorcontrib><title>Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries</title><title>Angewandte Chemie (International ed.)</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>A fluorine‐doped antiperovskite Li‐ion conductor Li2(OH)X (X=Cl, Br) is shown to be a promising candidate for a solid electrolyte in an all‐solid‐state Li‐ion rechargeable battery. Substitution of F− for OH− transforms orthorhombic Li2OHCl to a room‐temperature cubic phase, which shows electrochemical stability to 9 V versus Li+/Li and two orders of magnitude higher Li‐ion conductivity than that of orthorhombic Li2OHCl. An all‐solid‐state Li/LiFePO4 with F‐doped Li2OHCl as the solid electrolyte showed good cyclability and a high coulombic efficiency over 40 charge/discharge cycles.
Higher conductivity: A fluorine‐doped antiperovskite Li‐ion conductor Li2(OH)0.9F0.1Cl shows electrochemical stability up to 9 V versus Li+/Li and two orders of magnitude higher Li‐ion conductivity than that of orthorhombic Li2OHCl.</description><subject>all-solid-state battery</subject><subject>antiperovskite</subject><subject>Electrolytes</subject><subject>Energy Sciences</subject><subject>ENERGY STORAGE</subject><subject>Lithium</subject><subject>lithium-ion battery</subject><subject>solid electrolyte</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkc1vEzEUxC0EoqVw5YgiuHBx8Mfa3j2GkoaIqCBS4Gi59ovq1lkH2wvkv8fRlghxQT74yfrNaPwGoeeUTCkh7I3pPUwZoZI0QjQP0CkVjGKuFH9Y54ZzrFpBT9CTnG8r37ZEPkYnTHEhO8FP0foiDDH5HvC7uAM3mfXF7yDFH_nOF5jMA9iSYtjXeRPTZBYCXsfgHV4XU99Wvtz4YYuXsZ-8NaVA8pCfokcbEzI8u7_P0JeL-dX5e7z6uFiez1bYipY2mFFLWkmvW9VAzSs6Ak7xrjXSGttKZZ1zUhEruobbijFwjigpOmEUY3bDz9DL0Tfm4nW2NbC9sbHva2ZNm3q4rNDrEdql-H2AXPTWZwshmB7ikDVtKRGyrqap6Kt_0Ns4pL5-4UDRut-apFLTkbIp5pxgo3fJb03aa0r0oRN96EQfO6mCF_e2w_UW3BH_U0IFuhH46QPs_2OnZ5fL-d_meNT6XODXUWvSnZaKK6G_XS70gl99lh--Mv2J_wYzBaWi</recordid><startdate>20160816</startdate><enddate>20160816</enddate><creator>Li, Yutao</creator><creator>Zhou, Weidong</creator><creator>Xin, Sen</creator><creator>Li, Shuai</creator><creator>Zhu, Jinlong</creator><creator>Lü, Xujie</creator><creator>Cui, Zhiming</creator><creator>Jia, Quanxi</creator><creator>Zhou, Jianshi</creator><creator>Zhao, Yusheng</creator><creator>Goodenough, John B.</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>OIOZB</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000000311716437</orcidid><orcidid>https://orcid.org/0000000184027160</orcidid></search><sort><creationdate>20160816</creationdate><title>Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries</title><author>Li, Yutao ; Zhou, Weidong ; Xin, Sen ; Li, Shuai ; Zhu, Jinlong ; Lü, Xujie ; Cui, Zhiming ; Jia, Quanxi ; Zhou, Jianshi ; Zhao, Yusheng ; Goodenough, John B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5814-21c0861b874e773590ed7398a6cac867cddd670c5943c1b82edd076595a722cf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>all-solid-state battery</topic><topic>antiperovskite</topic><topic>Electrolytes</topic><topic>Energy Sciences</topic><topic>ENERGY STORAGE</topic><topic>Lithium</topic><topic>lithium-ion battery</topic><topic>solid electrolyte</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Yutao</creatorcontrib><creatorcontrib>Zhou, Weidong</creatorcontrib><creatorcontrib>Xin, Sen</creatorcontrib><creatorcontrib>Li, Shuai</creatorcontrib><creatorcontrib>Zhu, Jinlong</creatorcontrib><creatorcontrib>Lü, Xujie</creatorcontrib><creatorcontrib>Cui, Zhiming</creatorcontrib><creatorcontrib>Jia, Quanxi</creatorcontrib><creatorcontrib>Zhou, Jianshi</creatorcontrib><creatorcontrib>Zhao, Yusheng</creatorcontrib><creatorcontrib>Goodenough, John B.</creatorcontrib><creatorcontrib>Univ. of Nevada, Las Vegas, NV (United States)</creatorcontrib><creatorcontrib>Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Yutao</au><au>Zhou, Weidong</au><au>Xin, Sen</au><au>Li, Shuai</au><au>Zhu, Jinlong</au><au>Lü, Xujie</au><au>Cui, Zhiming</au><au>Jia, Quanxi</au><au>Zhou, Jianshi</au><au>Zhao, Yusheng</au><au>Goodenough, John B.</au><aucorp>Univ. of Nevada, Las Vegas, NV (United States)</aucorp><aucorp>Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2016-08-16</date><risdate>2016</risdate><volume>55</volume><issue>34</issue><spage>9965</spage><epage>9968</epage><pages>9965-9968</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>A fluorine‐doped antiperovskite Li‐ion conductor Li2(OH)X (X=Cl, Br) is shown to be a promising candidate for a solid electrolyte in an all‐solid‐state Li‐ion rechargeable battery. Substitution of F− for OH− transforms orthorhombic Li2OHCl to a room‐temperature cubic phase, which shows electrochemical stability to 9 V versus Li+/Li and two orders of magnitude higher Li‐ion conductivity than that of orthorhombic Li2OHCl. An all‐solid‐state Li/LiFePO4 with F‐doped Li2OHCl as the solid electrolyte showed good cyclability and a high coulombic efficiency over 40 charge/discharge cycles.
Higher conductivity: A fluorine‐doped antiperovskite Li‐ion conductor Li2(OH)0.9F0.1Cl shows electrochemical stability up to 9 V versus Li+/Li and two orders of magnitude higher Li‐ion conductivity than that of orthorhombic Li2OHCl.</abstract><cop>Germany</cop><pub>Blackwell Publishing Ltd</pub><pmid>27356953</pmid><doi>10.1002/anie.201604554</doi><tpages>4</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000000311716437</orcidid><orcidid>https://orcid.org/0000000184027160</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2016-08, Vol.55 (34), p.9965-9968 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_osti_scitechconnect_1414136 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | all-solid-state battery antiperovskite Electrolytes Energy Sciences ENERGY STORAGE Lithium lithium-ion battery solid electrolyte |
| title | Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T17%3A46%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fluorine-Doped%20Antiperovskite%20Electrolyte%20for%20All-Solid-State%20Lithium-Ion%20Batteries&rft.jtitle=Angewandte%20Chemie%20(International%20ed.)&rft.au=Li,%20Yutao&rft.aucorp=Univ.%20of%20Nevada,%20Las%20Vegas,%20NV%20(United%20States)&rft.date=2016-08-16&rft.volume=55&rft.issue=34&rft.spage=9965&rft.epage=9968&rft.pages=9965-9968&rft.issn=1433-7851&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.201604554&rft_dat=%3Cproquest_osti_%3E4148173761%3C/proquest_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1811554943&rft_id=info:pmid/27356953&rfr_iscdi=true |