Preparation of tetrafluoroethylene from the pyrolysis of pentafluoropropionate salts

Typical yields of TFE obtained from pyrolysis of potassium pentafluoropropionate obtained from the acid-base neutralization method are >98%. [Display omitted] •Equimolar mixtures of tetrafluoroethylene and carbon dioxide were prepared.•Higher yields of TFE than previous literature reports by this...

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Veröffentlicht in:	Journal of fluorine chemistry 2017-04, Vol.196 (C), p.107-116
Hauptverfasser:	Hercules, Daniel A., Parrish, Cameron A., Sayler, Todd S., Tice, Kevin T., Williams, Shane M., Lowery, Lauren E., Brady, Michael E., Coward, Robert B., Murphy, Justin A., Hey, Trevyn A., Scavuzzo, Anthony R., Rummler, Lucy M., Burns, Emory G., Matsnev, Andrej V., Fernandez, Richard E., McMillen, Colin D., Thrasher, Joseph S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acid-base neutralization Calorimetry Chemical compounds Chlorodifluoromethane Crystallography Differential scanning calorimetry Electron microscopy Fourier transforms Hazards Heat measurement Infrared spectrophotometers Institutions Mass spectrometry Mass spectroscopy Neutralization NMR Nuclear magnetic resonance Potassium Pyrolysis Salt Salts Scanning electron microscopy Single crystals Spectrophotometry Spectroscopy Synthesis and pyrolysis of potassium pentafluoropropionate Tetrafluoroethylene Tetrafluoroethylene (TFE) Tetrafluoroethylene-carbon dioxide mixture Thermal analysis Thermogravimetric analysis Use of TFE in academic institutions Vacuum X-ray crystallography X-ray diffraction
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