Mesoporous Manganese Oxide Catalyzed Aerobic Oxidative Coupling of Anilines To Aromatic Azo Compounds
Herein we introduce an environmentally friendly approach to the synthesis of symmetrical and asymmetrical aromatic azo compounds by using air as the sole oxidant under mild reaction conditions in the presence of cost‐effective and reusable mesoporous manganese oxide materials. Oxidans für umsonst: E...
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| Veröffentlicht in: | Angewandte Chemie 2016-02, Vol.128 (6), p.2211-2215 |
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| container_end_page | 2215 |
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| container_issue | 6 |
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| container_title | Angewandte Chemie |
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| creator | Dutta, Biswanath Biswas, Sourav Sharma, Vinit Savage, Nancy Ortins Alpay, S. Pamir Suib, Steven L. |
| description | Herein we introduce an environmentally friendly approach to the synthesis of symmetrical and asymmetrical aromatic azo compounds by using air as the sole oxidant under mild reaction conditions in the presence of cost‐effective and reusable mesoporous manganese oxide materials.
Oxidans für umsonst: Ein kosteneffektives und wiederverwendbares mesoporöses Manganoxidmaterial katalysiert die milde oxidative Kupplung von Anilinen mit elektronenschiebenden oder elektronenziehenden Substituenten zur Bildung von symmetrischen und unsymmetrischen Azobenzolen. Luft ist das einzige Oxidationsmittel in diesem umweltschonenden Prozess (siehe Bild; Mn violett, O grün). |
| doi_str_mv | 10.1002/ange.201508223 |
| format | Article |
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Oxidans für umsonst: Ein kosteneffektives und wiederverwendbares mesoporöses Manganoxidmaterial katalysiert die milde oxidative Kupplung von Anilinen mit elektronenschiebenden oder elektronenziehenden Substituenten zur Bildung von symmetrischen und unsymmetrischen Azobenzolen. Luft ist das einzige Oxidationsmittel in diesem umweltschonenden Prozess (siehe Bild; Mn violett, O grün).</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.201508223</identifier><language>eng</language><publisher>Weinheim: Blackwell Publishing Ltd</publisher><subject>Anilinoxidation ; Aromatic compounds ; Asymmetry ; Azo compounds ; Azoverbindungen ; Chemistry ; Coupling (molecular) ; Heterogene Katalyse ; Manganese ; Manganese compounds ; Manganese oxides ; Manganoxid ; Mesoporöse Materialien ; Oxidants ; Sole ; Synthesis (chemistry)</subject><ispartof>Angewandte Chemie, 2016-02, Vol.128 (6), p.2211-2215</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3943-4d6f4cf30735a6b19b35247ce41336851b444748b246b82922688320202c93233</citedby><cites>FETCH-LOGICAL-c3943-4d6f4cf30735a6b19b35247ce41336851b444748b246b82922688320202c93233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fange.201508223$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fange.201508223$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,776,780,881,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/1400453$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Dutta, Biswanath</creatorcontrib><creatorcontrib>Biswas, Sourav</creatorcontrib><creatorcontrib>Sharma, Vinit</creatorcontrib><creatorcontrib>Savage, Nancy Ortins</creatorcontrib><creatorcontrib>Alpay, S. Pamir</creatorcontrib><creatorcontrib>Suib, Steven L.</creatorcontrib><title>Mesoporous Manganese Oxide Catalyzed Aerobic Oxidative Coupling of Anilines To Aromatic Azo Compounds</title><title>Angewandte Chemie</title><addtitle>Angew. Chem</addtitle><description>Herein we introduce an environmentally friendly approach to the synthesis of symmetrical and asymmetrical aromatic azo compounds by using air as the sole oxidant under mild reaction conditions in the presence of cost‐effective and reusable mesoporous manganese oxide materials.
Oxidans für umsonst: Ein kosteneffektives und wiederverwendbares mesoporöses Manganoxidmaterial katalysiert die milde oxidative Kupplung von Anilinen mit elektronenschiebenden oder elektronenziehenden Substituenten zur Bildung von symmetrischen und unsymmetrischen Azobenzolen. Luft ist das einzige Oxidationsmittel in diesem umweltschonenden Prozess (siehe Bild; Mn violett, O grün).</description><subject>Anilinoxidation</subject><subject>Aromatic compounds</subject><subject>Asymmetry</subject><subject>Azo compounds</subject><subject>Azoverbindungen</subject><subject>Chemistry</subject><subject>Coupling (molecular)</subject><subject>Heterogene Katalyse</subject><subject>Manganese</subject><subject>Manganese compounds</subject><subject>Manganese oxides</subject><subject>Manganoxid</subject><subject>Mesoporöse Materialien</subject><subject>Oxidants</subject><subject>Sole</subject><subject>Synthesis (chemistry)</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkktv1DAUhSMEEkNhy9qCDZtM_Yofy2jUTpH6QFURS8vx3BSXTBzsBDr99TgNqhALkBe27v3Oke49Loq3BK8JxvTY9rewpphUWFHKnhUrUlFSMlnJ58UKY85LRbl-WbxK6Q5jLKjUqwIuIIUhxDAldJEdbA8J0NW93wHa2NF2hwfYoRpiaLx7rNvR_8i9MA2d729RaFHd-_yEhG4CqmPYZ8Kh-iFkaD-Eqd-l18WL1nYJ3vy-j4rPpyc3m7Py_Gr7cVOfl45pzkq-Ey13LcOSVVY0RDesolw64IQxoSrScM4lVw3lolFUUyqUYhTn4zSjjB0V7xbfkEZvkvMjuK8u9D240RCel1DN0IcFGmL4PkEazd4nB12XZ89rMERlTjOGZ_T9X-hdmGKfRzBEY0E0rbj6JyXFbKeZzNR6oVwMKUVozRD93saDIdjMAZo5QPMUYBboRfDTd3D4D23qy-3Jn9py0fo0wv2T1sZvRsj8JcyXy625PvsktMLMXLNfKzGqIA</recordid><startdate>20160205</startdate><enddate>20160205</enddate><creator>Dutta, Biswanath</creator><creator>Biswas, Sourav</creator><creator>Sharma, Vinit</creator><creator>Savage, Nancy Ortins</creator><creator>Alpay, S. 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Oxidans für umsonst: Ein kosteneffektives und wiederverwendbares mesoporöses Manganoxidmaterial katalysiert die milde oxidative Kupplung von Anilinen mit elektronenschiebenden oder elektronenziehenden Substituenten zur Bildung von symmetrischen und unsymmetrischen Azobenzolen. Luft ist das einzige Oxidationsmittel in diesem umweltschonenden Prozess (siehe Bild; Mn violett, O grün).</abstract><cop>Weinheim</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/ange.201508223</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Anilinoxidation Aromatic compounds Asymmetry Azo compounds Azoverbindungen Chemistry Coupling (molecular) Heterogene Katalyse Manganese Manganese compounds Manganese oxides Manganoxid Mesoporöse Materialien Oxidants Sole Synthesis (chemistry) |
| title | Mesoporous Manganese Oxide Catalyzed Aerobic Oxidative Coupling of Anilines To Aromatic Azo Compounds |
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