Multiple scaling power in liquid gallium under pressure conditions

Generally, a single scaling exponent, Df, can characterize the fractal structures of metallic glasses according to the scaling power law. However, when the scaling power law is applied to liquid gallium upon compression, the results show multiple scaling exponents and the values are beyond 3 within...

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Veröffentlicht in:Physical review. B 2017-06, Vol.95 (22)
Hauptverfasser: Li, Renfeng, Wang, Luhong, Li, Liangliang, Yu, Tony, Zhao, Haiyan, Chapman, Karena W., Rivers, Mark L., Chupas, Peter J., Mao, Ho-kwang, Liu, Haozhe
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container_issue 22
container_start_page
container_title Physical review. B
container_volume 95
creator Li, Renfeng
Wang, Luhong
Li, Liangliang
Yu, Tony
Zhao, Haiyan
Chapman, Karena W.
Rivers, Mark L.
Chupas, Peter J.
Mao, Ho-kwang
Liu, Haozhe
description Generally, a single scaling exponent, Df, can characterize the fractal structures of metallic glasses according to the scaling power law. However, when the scaling power law is applied to liquid gallium upon compression, the results show multiple scaling exponents and the values are beyond 3 within the first four coordination spheres in real space, indicating that the power law fails to describe the fractal feature in liquid gallium. The increase in the first coordination number with pressure leads to the fact that first coordination spheres at different pressures are not similar to each other in a geometrical sense. This multiple scaling power behavior is confined within a correlation length of ξ ≈ 14–15 Å at applied pressure according to decay of G(r) in liquid gallium. Beyond this length the liquid gallium system could roughly be viewed as homogeneous, as indicated by the scaling exponent, Ds, which is close to 3 beyond the first four coordination spheres.
doi_str_mv 10.1103/PhysRevB.95.224204
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