Biomass-Derived Butadiene by Dehydra-Decyclization of Tetrahydrofuran
Catalytic ring-opening dehydration of tetrahydrofuran (THF), itself a product of decarbonylation and reduction of biomass-derived furfural, yields 1,3-butadiene, an important monomer in rubbers and elastomers. It is demonstrated that dehydra-decyclization of THF with phosphorus-containing siliceous...
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| Veröffentlicht in: | ACS sustainable chemistry & engineering 2017-05, Vol.5 (5), p.3732-3736 |
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| creator | Abdelrahman, Omar A Park, Dae Sung Vinter, Katherine P Spanjers, Charles S Ren, Limin Cho, Hong Je Vlachos, Dionisios G Fan, Wei Tsapatsis, Michael Dauenhauer, Paul J |
| description | Catalytic ring-opening dehydration of tetrahydrofuran (THF), itself a product of decarbonylation and reduction of biomass-derived furfural, yields 1,3-butadiene, an important monomer in rubbers and elastomers. It is demonstrated that dehydra-decyclization of THF with phosphorus-containing siliceous self-pillared pentasil (SPP) or MFI structure exhibits high selectivity to butadiene (85–99%) at both low (9%) and high (89%) conversion of THF. High selectivity to pentadiene and hexadiene was also obtained from 2-methyl-tetrahydrofuran and 2,5-dimethyl-tetrahydrofuran, respectively, with phosphorus-containing, all-silica zeolites. |
| doi_str_mv | 10.1021/acssuschemeng.7b00745 |
| format | Article |
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Eng</addtitle><date>2017-05-01</date><risdate>2017</risdate><volume>5</volume><issue>5</issue><spage>3732</spage><epage>3736</epage><pages>3732-3736</pages><issn>2168-0485</issn><eissn>2168-0485</eissn><abstract>Catalytic ring-opening dehydration of tetrahydrofuran (THF), itself a product of decarbonylation and reduction of biomass-derived furfural, yields 1,3-butadiene, an important monomer in rubbers and elastomers. It is demonstrated that dehydra-decyclization of THF with phosphorus-containing siliceous self-pillared pentasil (SPP) or MFI structure exhibits high selectivity to butadiene (85–99%) at both low (9%) and high (89%) conversion of THF. 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| subjects | catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing) |
| title | Biomass-Derived Butadiene by Dehydra-Decyclization of Tetrahydrofuran |
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