A metal-organic framework immobilised iridium pincer complex
An iridium pincer complex has been immobilised in the metal-organic framework NU-1000 using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formati...
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| Veröffentlicht in: | Chemical science (Cambridge) 2016-01, Vol.7 (8), p.498-4984 |
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| creator | Rimoldi, Martino Nakamura, Akitake Vermeulen, Nicolaas A Henkelis, James J Blackburn, Anthea K Hupp, Joseph T Stoddart, J. Fraser Farha, Omar K |
| description | An iridium pincer complex has been immobilised in the metal-organic framework
NU-1000
using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formation of the catalytically active iridium dihydride. The Ir-pincer modified
NU-1000
is an active catalyst for the condensed phase hydrogenation of a liquid alkene (1-decene and styrene) and shows enhanced activity with respect to a homogeneous analogue. Additionally, the Ir-pincer immobilised inside
NU-1000
operated as an efficient heterogenous catalyst under flow conditions.
An iridium pincer complex has been immobilised in the metal-organic framework
NU-1000
. The stable Ir-pincer modified
NU-1000
is catalytically active in the hydrogenation of alkenes in condensed phase and under flow conditions. |
| doi_str_mv | 10.1039/c6sc01376g |
| format | Article |
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NU-1000
using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formation of the catalytically active iridium dihydride. The Ir-pincer modified
NU-1000
is an active catalyst for the condensed phase hydrogenation of a liquid alkene (1-decene and styrene) and shows enhanced activity with respect to a homogeneous analogue. Additionally, the Ir-pincer immobilised inside
NU-1000
operated as an efficient heterogenous catalyst under flow conditions.
An iridium pincer complex has been immobilised in the metal-organic framework
NU-1000
. The stable Ir-pincer modified
NU-1000
is catalytically active in the hydrogenation of alkenes in condensed phase and under flow conditions.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/c6sc01376g</identifier><identifier>PMID: 30155148</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>catalysis (heterogeneous), materials and chemistry by design, synthesis (novel materials) ; Catalysts ; Chemistry ; Hydrogenation ; Iridium ; Iridium compounds ; Liquids ; Metal-organic frameworks ; Olefins ; Solvents</subject><ispartof>Chemical science (Cambridge), 2016-01, Vol.7 (8), p.498-4984</ispartof><rights>This journal is © The Royal Society of Chemistry 2016 2016</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c460t-95a9ada3d936b47354ca4e932c55a8081c7d6b5e5f53cda207cafad4adf193753</citedby><cites>FETCH-LOGICAL-c460t-95a9ada3d936b47354ca4e932c55a8081c7d6b5e5f53cda207cafad4adf193753</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6018438/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6018438/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27903,27904,53769,53771</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30155148$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/1388851$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Rimoldi, Martino</creatorcontrib><creatorcontrib>Nakamura, Akitake</creatorcontrib><creatorcontrib>Vermeulen, Nicolaas A</creatorcontrib><creatorcontrib>Henkelis, James J</creatorcontrib><creatorcontrib>Blackburn, Anthea K</creatorcontrib><creatorcontrib>Hupp, Joseph T</creatorcontrib><creatorcontrib>Stoddart, J. Fraser</creatorcontrib><creatorcontrib>Farha, Omar K</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)</creatorcontrib><title>A metal-organic framework immobilised iridium pincer complex</title><title>Chemical science (Cambridge)</title><addtitle>Chem Sci</addtitle><description>An iridium pincer complex has been immobilised in the metal-organic framework
NU-1000
using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formation of the catalytically active iridium dihydride. The Ir-pincer modified
NU-1000
is an active catalyst for the condensed phase hydrogenation of a liquid alkene (1-decene and styrene) and shows enhanced activity with respect to a homogeneous analogue. Additionally, the Ir-pincer immobilised inside
NU-1000
operated as an efficient heterogenous catalyst under flow conditions.
An iridium pincer complex has been immobilised in the metal-organic framework
NU-1000
. The stable Ir-pincer modified
NU-1000
is catalytically active in the hydrogenation of alkenes in condensed phase and under flow conditions.</description><subject>catalysis (heterogeneous), materials and chemistry by design, synthesis (novel materials)</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Hydrogenation</subject><subject>Iridium</subject><subject>Iridium compounds</subject><subject>Liquids</subject><subject>Metal-organic frameworks</subject><subject>Olefins</subject><subject>Solvents</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFks9rFTEQx4MottRevCuLJxFWk00mm4AUyqNWoeBBPYd5k-xrdLN5Jvv88d9366tPPTmXGZgP35nhO4w9Fvyl4NK-Il2JC9nrzT123HElWg3S3j_UHT9ip7V-5ktIKaDrH7IjyQWAUOaYvT5vUphxbHPZ4BSpGQqm8D2XL01MKa_jGGvwTSzRx11qtnGiUBrKaTuGH4_YgwHHGk7v8gn79Obi4-pte_X-8t3q_KolpfncWkCLHqW3Uq9VL0ERqmBlRwBouBHUe72GAANI8tjxnnBAr9APwsoe5Ak72-tud-sUPIVpLji6bYkJy0-XMbp_O1O8dpv8zWkujJJmEXi2F8h1jq5SnANdU56mQLMT0hgDYoGe300p-esu1NmlWCmMI04h76rruNUAvFP_R4WRAGCVud39xR6lkmstYTisLbi7ddCt9IfVLwcvF_jp34ce0N9-LcCTPVAqHbp_XkDeAANKoBQ</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Rimoldi, Martino</creator><creator>Nakamura, Akitake</creator><creator>Vermeulen, Nicolaas A</creator><creator>Henkelis, James J</creator><creator>Blackburn, Anthea K</creator><creator>Hupp, Joseph T</creator><creator>Stoddart, J. Fraser</creator><creator>Farha, Omar K</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>OTOTI</scope><scope>5PM</scope></search><sort><creationdate>20160101</creationdate><title>A metal-organic framework immobilised iridium pincer complex</title><author>Rimoldi, Martino ; Nakamura, Akitake ; Vermeulen, Nicolaas A ; Henkelis, James J ; Blackburn, Anthea K ; Hupp, Joseph T ; Stoddart, J. Fraser ; Farha, Omar K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c460t-95a9ada3d936b47354ca4e932c55a8081c7d6b5e5f53cda207cafad4adf193753</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>catalysis (heterogeneous), materials and chemistry by design, synthesis (novel materials)</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Hydrogenation</topic><topic>Iridium</topic><topic>Iridium compounds</topic><topic>Liquids</topic><topic>Metal-organic frameworks</topic><topic>Olefins</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rimoldi, Martino</creatorcontrib><creatorcontrib>Nakamura, Akitake</creatorcontrib><creatorcontrib>Vermeulen, Nicolaas A</creatorcontrib><creatorcontrib>Henkelis, James J</creatorcontrib><creatorcontrib>Blackburn, Anthea K</creatorcontrib><creatorcontrib>Hupp, Joseph T</creatorcontrib><creatorcontrib>Stoddart, J. Fraser</creatorcontrib><creatorcontrib>Farha, Omar K</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rimoldi, Martino</au><au>Nakamura, Akitake</au><au>Vermeulen, Nicolaas A</au><au>Henkelis, James J</au><au>Blackburn, Anthea K</au><au>Hupp, Joseph T</au><au>Stoddart, J. Fraser</au><au>Farha, Omar K</au><aucorp>Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A metal-organic framework immobilised iridium pincer complex</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>7</volume><issue>8</issue><spage>498</spage><epage>4984</epage><pages>498-4984</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>An iridium pincer complex has been immobilised in the metal-organic framework
NU-1000
using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formation of the catalytically active iridium dihydride. The Ir-pincer modified
NU-1000
is an active catalyst for the condensed phase hydrogenation of a liquid alkene (1-decene and styrene) and shows enhanced activity with respect to a homogeneous analogue. Additionally, the Ir-pincer immobilised inside
NU-1000
operated as an efficient heterogenous catalyst under flow conditions.
An iridium pincer complex has been immobilised in the metal-organic framework
NU-1000
. The stable Ir-pincer modified
NU-1000
is catalytically active in the hydrogenation of alkenes in condensed phase and under flow conditions.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30155148</pmid><doi>10.1039/c6sc01376g</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; PubMed Central |
| subjects | catalysis (heterogeneous), materials and chemistry by design, synthesis (novel materials) Catalysts Chemistry Hydrogenation Iridium Iridium compounds Liquids Metal-organic frameworks Olefins Solvents |
| title | A metal-organic framework immobilised iridium pincer complex |
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