Tin-Free Direct C–H Arylation Polymerization for High Photovoltaic Efficiency Conjugated Copolymers

A new and highly regioselective direct C–H arylation polymerization (DARP) methodology enables the reproducible and sustainable synthesis of high-performance π-conjugated photovoltaic copolymers. Unlike traditional Stille polycondensation methods for producing photovoltaic copolymers, this DARP prot...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-12, Vol.138 (48), p.15699-15709
Hauptverfasser:	Dudnik, Alexander S, Aldrich, Thomas J, Eastham, Nicholas D, Chang, Robert P. H, Facchetti, Antonio, Marks, Tobin J
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), bio-inspired, hydrogen and fuel cells, electrodes - solar, defects, charge transport, spin dynamics, membrane, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)
Online-Zugang:	Volltext
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