Thermodynamic complexity of carbon capture in alkylamine-functionalized metal–organic frameworks

For coordinatively unsaturated metal-organic frameworks (MOFs), the metal centers can be functionalized as CO sub(2) capture/storage adsorbents by grafting species having specific active groups. We report direct measurement of enthalpy of adsorption of CO sub(2) on an alkylamine-appended MOF, mmen-M...

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Veröffentlicht in:	Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-01, Vol.3 (8), p.4248-4254
Hauptverfasser:	Wu, D, McDonald, T M, Quan, Z, Ushakov, S V, Zhang, P, Long, J R, Navrotsky, A
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorbents Adsorption Calorimetry Carbon capture and storage Carbon dioxide Chemisorption Enthalpy Entropy membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing) Metal-organic frameworks Sustainability
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