Selection Criteria and Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Advanced Spark-Ignition Engines
We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was cr...
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Veröffentlicht in: | SAE International journal of fuels and lubricants 2017-06, Vol.10 (2), p.442-460, Article 2017-01-0868 |
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creator | McCormick, Robert L. Fioroni, Gina Fouts, Lisa Christensen, Earl Yanowitz, Janet Polikarpov, Evgueni Albrecht, Karl Gaspar, Daniel J. Gladden, John George, Anthe |
description | We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) |
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A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins. Compounds predicted to be less anaerobically biodegradable than methyl-tert-butyl ether with water solubility greater than 10,000 mg/L were also eliminated. A minimum Research octane number (RON) of 98 was applied. These criteria produced a list of 40 bioblendstocks with promising properties. Additional property data, including Motor octane number (MON), heat of vaporization, and lower heating value, were acquired for these bioblendstocks. A subset of the bioblendstocks representing all functional groups were blended into gasoline or a gasoline surrogate to measure their effect on vapor pressure, distillation curve, oxidation stability, RON, and MON. For blending into a conventional or reformulated blendstock for E10 blending, ethanol, 2-butanol, isobutanol, and diisobutylene have the most desirable properties for blending of a high-octane advanced SI engine fuel.</description><identifier>ISSN: 1946-3952</identifier><identifier>ISSN: 1946-3960</identifier><identifier>EISSN: 1946-3960</identifier><identifier>DOI: 10.4271/2017-01-0868</identifier><language>eng</language><publisher>United States: SAE International</publisher><subject>09 BIOMASS FUELS ; Analysis ; biofuel ; Biomass energy ; Engines ; fuel properties ; gasoline ; Ignition systems ; Materials ; Octane ratings ; spark-ignition</subject><ispartof>SAE International journal of fuels and lubricants, 2017-06, Vol.10 (2), p.442-460, Article 2017-01-0868</ispartof><rights>null</rights><rights>COPYRIGHT 2017 SAE International</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c459t-ef06db1f998e7d1d3c4b018918ed3724233899da2d097aab723b7d08f450c8ae3</citedby><cites>FETCH-LOGICAL-c459t-ef06db1f998e7d1d3c4b018918ed3724233899da2d097aab723b7d08f450c8ae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.jstor.org/stable/pdf/26274125$$EPDF$$P50$$Gjstor$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/26274125$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>230,314,776,780,799,881,27901,27902,57992,58225</link.rule.ids><backlink>$$Uhttps://www.osti.gov/servlets/purl/1378889$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>McCormick, Robert L.</creatorcontrib><creatorcontrib>Fioroni, Gina</creatorcontrib><creatorcontrib>Fouts, Lisa</creatorcontrib><creatorcontrib>Christensen, Earl</creatorcontrib><creatorcontrib>Yanowitz, Janet</creatorcontrib><creatorcontrib>Polikarpov, Evgueni</creatorcontrib><creatorcontrib>Albrecht, Karl</creatorcontrib><creatorcontrib>Gaspar, Daniel J.</creatorcontrib><creatorcontrib>Gladden, John</creatorcontrib><creatorcontrib>George, Anthe</creatorcontrib><creatorcontrib>National Renewable Energy Laboratory (NREL), Golden, CO (United States)</creatorcontrib><title>Selection Criteria and Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Advanced Spark-Ignition Engines</title><title>SAE International journal of fuels and lubricants</title><description>We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins. Compounds predicted to be less anaerobically biodegradable than methyl-tert-butyl ether with water solubility greater than 10,000 mg/L were also eliminated. A minimum Research octane number (RON) of 98 was applied. These criteria produced a list of 40 bioblendstocks with promising properties. Additional property data, including Motor octane number (MON), heat of vaporization, and lower heating value, were acquired for these bioblendstocks. A subset of the bioblendstocks representing all functional groups were blended into gasoline or a gasoline surrogate to measure their effect on vapor pressure, distillation curve, oxidation stability, RON, and MON. For blending into a conventional or reformulated blendstock for E10 blending, ethanol, 2-butanol, isobutanol, and diisobutylene have the most desirable properties for blending of a high-octane advanced SI engine fuel.</description><subject>09 BIOMASS FUELS</subject><subject>Analysis</subject><subject>biofuel</subject><subject>Biomass energy</subject><subject>Engines</subject><subject>fuel properties</subject><subject>gasoline</subject><subject>Ignition systems</subject><subject>Materials</subject><subject>Octane ratings</subject><subject>spark-ignition</subject><issn>1946-3952</issn><issn>1946-3960</issn><issn>1946-3960</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNptkc9rFTEQxxexYK3evApBr27Nj91Ncnw-Wy0UWmg9h3nJ7DOvu0lJ0oIH_3ezrhQUmcMMyWe-w8y3ad4wetpxyT5yymRLWUvVoJ41x0x3Qyv0QJ8_1T1_0bzM-UDpIKlgx83PG5zQFh8D2SZfMHkgEBy5sQkx-LAncSTXsWAoHibyyccZcm4_V_ARK1YSwpwJZHL-gPV_wuByifYukzEmsnGPEOwC3kO6ay_2wf-edRb2PmB-1RyNMGV8_SefNN_Oz263X9vLqy8X281la7telxZHOrgdG7VWKB1zwnY7ypRmCp2QvONCKK0dcEe1BNhJLnbSUTV2PbUKUJw071bdmIs32dZF7XcbQ6irGyakUkpX6P0K7WFC48MYSwI7-2zNphecci6FqNTpf6gaDmdfJXH09f2vhg9rg00x54SjuU9-hvTDMGoW28xim6HMLLZVvF3xDIt8dSTAcjKYDvGh1lP-l3-78od69vSkzQcuO8Z78QtWyaKX</recordid><startdate>20170601</startdate><enddate>20170601</enddate><creator>McCormick, Robert L.</creator><creator>Fioroni, Gina</creator><creator>Fouts, Lisa</creator><creator>Christensen, Earl</creator><creator>Yanowitz, Janet</creator><creator>Polikarpov, Evgueni</creator><creator>Albrecht, Karl</creator><creator>Gaspar, Daniel J.</creator><creator>Gladden, John</creator><creator>George, Anthe</creator><general>SAE International</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OIOZB</scope><scope>OTOTI</scope></search><sort><creationdate>20170601</creationdate><title>Selection Criteria and Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Advanced Spark-Ignition Engines</title><author>McCormick, Robert L. ; Fioroni, Gina ; Fouts, Lisa ; Christensen, Earl ; Yanowitz, Janet ; Polikarpov, Evgueni ; Albrecht, Karl ; Gaspar, Daniel J. ; Gladden, John ; George, Anthe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c459t-ef06db1f998e7d1d3c4b018918ed3724233899da2d097aab723b7d08f450c8ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>09 BIOMASS FUELS</topic><topic>Analysis</topic><topic>biofuel</topic><topic>Biomass energy</topic><topic>Engines</topic><topic>fuel properties</topic><topic>gasoline</topic><topic>Ignition systems</topic><topic>Materials</topic><topic>Octane ratings</topic><topic>spark-ignition</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>McCormick, Robert L.</creatorcontrib><creatorcontrib>Fioroni, Gina</creatorcontrib><creatorcontrib>Fouts, Lisa</creatorcontrib><creatorcontrib>Christensen, Earl</creatorcontrib><creatorcontrib>Yanowitz, Janet</creatorcontrib><creatorcontrib>Polikarpov, Evgueni</creatorcontrib><creatorcontrib>Albrecht, Karl</creatorcontrib><creatorcontrib>Gaspar, Daniel J.</creatorcontrib><creatorcontrib>Gladden, John</creatorcontrib><creatorcontrib>George, Anthe</creatorcontrib><creatorcontrib>National Renewable Energy Laboratory (NREL), Golden, CO (United States)</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>SAE International journal of fuels and lubricants</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>McCormick, Robert L.</au><au>Fioroni, Gina</au><au>Fouts, Lisa</au><au>Christensen, Earl</au><au>Yanowitz, Janet</au><au>Polikarpov, Evgueni</au><au>Albrecht, Karl</au><au>Gaspar, Daniel J.</au><au>Gladden, John</au><au>George, Anthe</au><aucorp>National Renewable Energy Laboratory (NREL), Golden, CO (United States)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selection Criteria and Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Advanced Spark-Ignition Engines</atitle><jtitle>SAE International journal of fuels and lubricants</jtitle><date>2017-06-01</date><risdate>2017</risdate><volume>10</volume><issue>2</issue><spage>442</spage><epage>460</epage><pages>442-460</pages><artnum>2017-01-0868</artnum><issn>1946-3952</issn><issn>1946-3960</issn><eissn>1946-3960</eissn><abstract>We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. 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subjects | 09 BIOMASS FUELS Analysis biofuel Biomass energy Engines fuel properties gasoline Ignition systems Materials Octane ratings spark-ignition |
title | Selection Criteria and Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Advanced Spark-Ignition Engines |
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