Modeling approach to identify physically distinct processes convoluted in electrochemical impedance spectra for proton-conducting solid oxide fuel cells
Electrochemical impedance spectroscopy (EIS) is an important characterization technique for solid oxide fuel cells (SOFCs); however, the overlap or dispersion in the frequency domain among physically distinct processes imposes great difficulties on unambiguous interpretation of EIS data. Built upon...
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Veröffentlicht in: | Journal of applied electrochemistry 2014-06, Vol.44 (6), p.683-694 |
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description | Electrochemical impedance spectroscopy (EIS) is an important characterization technique for solid oxide fuel cells (SOFCs); however, the overlap or dispersion in the frequency domain among physically distinct processes imposes great difficulties on unambiguous interpretation of EIS data. Built upon mechanistic SOFC model development and calibrations using polarization curve and multiple EIS curves under different operating voltages, a process reduction strategy was studied to identify both magnitude and frequencies of physically distinct processes convoluted in EIS. |
doi_str_mv | 10.1007/s10800-014-0682-2 |
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Heterogeneous Functional Materials Center (HeteroFoaM)</creatorcontrib><description>Electrochemical impedance spectroscopy (EIS) is an important characterization technique for solid oxide fuel cells (SOFCs); however, the overlap or dispersion in the frequency domain among physically distinct processes imposes great difficulties on unambiguous interpretation of EIS data. Built upon mechanistic SOFC model development and calibrations using polarization curve and multiple EIS curves under different operating voltages, a process reduction strategy was studied to identify both magnitude and frequencies of physically distinct processes convoluted in EIS.</description><identifier>ISSN: 0021-891X</identifier><identifier>EISSN: 1572-8838</identifier><identifier>DOI: 10.1007/s10800-014-0682-2</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Calibration ; Chemistry ; Chemistry and Materials Science ; Dispersions ; Electric potential ; Electrochemical impedance spectroscopy ; Electrochemistry ; Fuel cells ; Industrial Chemistry/Chemical Engineering ; Physical Chemistry ; Research Article ; Solid oxide fuel cells ; Spectra ; Strategy ; Voltage</subject><ispartof>Journal of applied electrochemistry, 2014-06, Vol.44 (6), p.683-694</ispartof><rights>Springer Science+Business Media Dordrecht 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-d722541d0820157e25f3b39141388a1c8e5d7e4e69c7d2fadc6fead8764d4f43</citedby><cites>FETCH-LOGICAL-c422t-d722541d0820157e25f3b39141388a1c8e5d7e4e69c7d2fadc6fead8764d4f43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10800-014-0682-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10800-014-0682-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,778,782,883,27907,27908,41471,42540,51302</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/1370157$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Shi, Junxiang</creatorcontrib><creatorcontrib>Xue, Xingjian</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC) (United States). Heterogeneous Functional Materials Center (HeteroFoaM)</creatorcontrib><title>Modeling approach to identify physically distinct processes convoluted in electrochemical impedance spectra for proton-conducting solid oxide fuel cells</title><title>Journal of applied electrochemistry</title><addtitle>J Appl Electrochem</addtitle><description>Electrochemical impedance spectroscopy (EIS) is an important characterization technique for solid oxide fuel cells (SOFCs); however, the overlap or dispersion in the frequency domain among physically distinct processes imposes great difficulties on unambiguous interpretation of EIS data. Built upon mechanistic SOFC model development and calibrations using polarization curve and multiple EIS curves under different operating voltages, a process reduction strategy was studied to identify both magnitude and frequencies of physically distinct processes convoluted in EIS.</description><subject>Calibration</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dispersions</subject><subject>Electric potential</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemistry</subject><subject>Fuel cells</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Physical Chemistry</subject><subject>Research Article</subject><subject>Solid oxide fuel cells</subject><subject>Spectra</subject><subject>Strategy</subject><subject>Voltage</subject><issn>0021-891X</issn><issn>1572-8838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1TAQhS1EJS4tD8DOYsXGre04ibNEFT-VWrHpgp1l7HGvK187ZBzEfRMeF0dhDatZzHdmzswh5K3g14Lz8QYF15wzLhTjg5ZMviAH0Y-Sad3pl-TAuRRMT-LbK_Ia8ZlzPslBHcjvh-IhxfxE7TwvxbojrYVGD7nGcKbz8YzR2ZTO1EesMbtKG-YAEZC6kn-WtFbwNGYKCVxtvSOcNgmNpxm8zQ4ozlvH0lCWTV1LZk3qV1e3xVhS9LT8aktpWCFRBynhFbkINiG8-VsvyeOnj4-3X9j91893tx_umVNSVuZHKXslPNeSt3tB9qH73k1CiU5rK5yG3o-gYJjc6GWw3g0BrNfjoLwKqrsk7_axpV1n0MUK7tjM5ebYiG7chjbo_Q418z9WwGpOETeXNkNZ0YhxkEJJ3k__R_t-GqZJD6KhYkfdUhAXCGZe4skuZyO42UI1e6imhWq2UI1sGrlrsLH5CRbzXNYltwf9Q_QHyHKoKg</recordid><startdate>20140601</startdate><enddate>20140601</enddate><creator>Shi, Junxiang</creator><creator>Xue, Xingjian</creator><general>Springer Netherlands</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>JG9</scope><scope>KR7</scope><scope>L7M</scope><scope>OTOTI</scope></search><sort><creationdate>20140601</creationdate><title>Modeling approach to identify physically distinct processes convoluted in electrochemical impedance spectra for proton-conducting solid oxide fuel cells</title><author>Shi, Junxiang ; Xue, Xingjian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-d722541d0820157e25f3b39141388a1c8e5d7e4e69c7d2fadc6fead8764d4f43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Calibration</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dispersions</topic><topic>Electric potential</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemistry</topic><topic>Fuel cells</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Physical Chemistry</topic><topic>Research Article</topic><topic>Solid oxide fuel cells</topic><topic>Spectra</topic><topic>Strategy</topic><topic>Voltage</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shi, Junxiang</creatorcontrib><creatorcontrib>Xue, Xingjian</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC) (United States). Heterogeneous Functional Materials Center (HeteroFoaM)</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Journal of applied electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shi, Junxiang</au><au>Xue, Xingjian</au><aucorp>Energy Frontier Research Centers (EFRC) (United States). Heterogeneous Functional Materials Center (HeteroFoaM)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Modeling approach to identify physically distinct processes convoluted in electrochemical impedance spectra for proton-conducting solid oxide fuel cells</atitle><jtitle>Journal of applied electrochemistry</jtitle><stitle>J Appl Electrochem</stitle><date>2014-06-01</date><risdate>2014</risdate><volume>44</volume><issue>6</issue><spage>683</spage><epage>694</epage><pages>683-694</pages><issn>0021-891X</issn><eissn>1572-8838</eissn><abstract>Electrochemical impedance spectroscopy (EIS) is an important characterization technique for solid oxide fuel cells (SOFCs); however, the overlap or dispersion in the frequency domain among physically distinct processes imposes great difficulties on unambiguous interpretation of EIS data. Built upon mechanistic SOFC model development and calibrations using polarization curve and multiple EIS curves under different operating voltages, a process reduction strategy was studied to identify both magnitude and frequencies of physically distinct processes convoluted in EIS.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10800-014-0682-2</doi><tpages>12</tpages></addata></record> |
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subjects | Calibration Chemistry Chemistry and Materials Science Dispersions Electric potential Electrochemical impedance spectroscopy Electrochemistry Fuel cells Industrial Chemistry/Chemical Engineering Physical Chemistry Research Article Solid oxide fuel cells Spectra Strategy Voltage |
title | Modeling approach to identify physically distinct processes convoluted in electrochemical impedance spectra for proton-conducting solid oxide fuel cells |
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