Photoionization Efficiencies of Five Polycyclic Aromatic Hydrocarbons
We have measured photoionization-efficiency curves for pyrene, fluoranthene, chrysene, perylene, and coronene in the photon energy range of 7.5–10.2 eV and derived their photoionization cross-section curves in this energy range. All measurements were performed using tunable vacuum ultraviolet (VUV)...
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| Veröffentlicht in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2017-06, Vol.121 (23), p.4447-4454 |
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| container_title | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory |
| container_volume | 121 |
| creator | Johansson, K. Olof Campbell, Matthew F Elvati, Paolo Schrader, Paul E Zádor, Judit Richards-Henderson, Nicole K Wilson, Kevin R Violi, Angela Michelsen, Hope A |
| description | We have measured photoionization-efficiency curves for pyrene, fluoranthene, chrysene, perylene, and coronene in the photon energy range of 7.5–10.2 eV and derived their photoionization cross-section curves in this energy range. All measurements were performed using tunable vacuum ultraviolet (VUV) radiation generated at the Advanced Light Source synchrotron at Lawrence Berkeley National Laboratory. The VUV radiation was used for photoionization, and detection was performed using a time-of-flight mass spectrometer. We measured the photoionization efficiency of 2,5-dimethylfuran simultaneously with those of pyrene, fluoranthene, chrysene, perylene, and coronene to obtain references of the photon flux during each measurement from the known photoionization cross-section curve of 2,5-dimethylfuran. |
| doi_str_mv | 10.1021/acs.jpca.7b02991 |
| format | Article |
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Olof ; Campbell, Matthew F ; Elvati, Paolo ; Schrader, Paul E ; Zádor, Judit ; Richards-Henderson, Nicole K ; Wilson, Kevin R ; Violi, Angela ; Michelsen, Hope A</creator><creatorcontrib>Johansson, K. Olof ; Campbell, Matthew F ; Elvati, Paolo ; Schrader, Paul E ; Zádor, Judit ; Richards-Henderson, Nicole K ; Wilson, Kevin R ; Violi, Angela ; Michelsen, Hope A ; Sandia National Lab. (SNL-CA), Livermore, CA (United States) ; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)</creatorcontrib><description>We have measured photoionization-efficiency curves for pyrene, fluoranthene, chrysene, perylene, and coronene in the photon energy range of 7.5–10.2 eV and derived their photoionization cross-section curves in this energy range. All measurements were performed using tunable vacuum ultraviolet (VUV) radiation generated at the Advanced Light Source synchrotron at Lawrence Berkeley National Laboratory. The VUV radiation was used for photoionization, and detection was performed using a time-of-flight mass spectrometer. We measured the photoionization efficiency of 2,5-dimethylfuran simultaneously with those of pyrene, fluoranthene, chrysene, perylene, and coronene to obtain references of the photon flux during each measurement from the known photoionization cross-section curve of 2,5-dimethylfuran.</description><identifier>ISSN: 1089-5639</identifier><identifier>EISSN: 1520-5215</identifier><identifier>DOI: 10.1021/acs.jpca.7b02991</identifier><identifier>PMID: 28521096</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY</subject><ispartof>The journal of physical chemistry. 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| title | Photoionization Efficiencies of Five Polycyclic Aromatic Hydrocarbons |
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