Deposition reactors for solar grade silicon: A comparative thermal analysis of a Siemens reactor and a fluidized bed reactor
Polysilicon production costs contribute approximately to 25–33% of the overall cost of the solar panels and a similar fraction of the total energy invested in their fabrication. Understanding the energy losses and the behaviour of process temperature is an essential requirement as one moves forward...
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description | Polysilicon production costs contribute approximately to 25–33% of the overall cost of the solar panels and a similar fraction of the total energy invested in their fabrication. Understanding the energy losses and the behaviour of process temperature is an essential requirement as one moves forward to design and build large scale polysilicon manufacturing plants. In this paper we present thermal models for two processes for poly production, viz., the Siemens process using trichlorosilane (TCS) as precursor and the fluid bed process using silane (monosilane, MS). We validate the models with some experimental measurements on prototype laboratory reactors relating the temperature profiles to product quality. A model sensitivity analysis is also performed, and the effects of some key parameters such as reactor wall emissivity and gas distributor temperature, on temperature distribution and product quality are examined. The information presented in this paper is useful for further understanding of the strengths and weaknesses of both deposition technologies, and will help in optimal temperature profiling of these systems aiming at lowering production costs without compromising the solar cell quality.
•Temperature control in the CVD processes for SoGSi production is essential.•The heat loss problem associated with polysilicon CVD is addressed.•CFD models for a Siemens and FBR prototypes are developed.•The CFD models developed give us reasonable estimates of the temperature distribution.•CFD models become a tool for design and will help in optimal temperature profiling of these systems. |
doi_str_mv | 10.1016/j.jcrysgro.2015.08.023 |
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•Temperature control in the CVD processes for SoGSi production is essential.•The heat loss problem associated with polysilicon CVD is addressed.•CFD models for a Siemens and FBR prototypes are developed.•The CFD models developed give us reasonable estimates of the temperature distribution.•CFD models become a tool for design and will help in optimal temperature profiling of these systems.</description><identifier>ISSN: 0022-0248</identifier><identifier>EISSN: 1873-5002</identifier><identifier>DOI: 10.1016/j.jcrysgro.2015.08.023</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>A1. CFD modelling ; A3. CVD reactors ; A3. CVD reactors B2. Polysilicon B2. Solar grade silicon A3. Siemens process Fluidized bed reactor A1. CFD modelling ; A3. Siemens process ; B2. Polysilicon ; B2. Solar grade silicon ; Deposition ; Energia solar ; Energia solar fotovoltaica ; Energia solar tèrmica ; Energies ; Fluidized bed reactor ; Industrial engineering ; Manufacturing engineering ; Mathematical models ; Production costs ; Reactors ; Sensitivity analysis ; Solar energy ; Thermal analysis ; Àrees temàtiques de la UPC</subject><ispartof>Journal of crystal growth, 2015-12, Vol.431 (C), p.1-9</ispartof><rights>2015 Elsevier B.V.</rights><rights>Attribution-NonCommercial-NoDerivs 3.0 Spain info:eu-repo/semantics/openAccess <a href="http://creativecommons.org/licenses/by-nc-nd/3.0/es/">http://creativecommons.org/licenses/by-nc-nd/3.0/es/</a></rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c565t-98109a9155cfffc0a86270aa708c9ded3f8d2cca3d0ed8159351c4d76c6d561e3</citedby><cites>FETCH-LOGICAL-c565t-98109a9155cfffc0a86270aa708c9ded3f8d2cca3d0ed8159351c4d76c6d561e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0022024815005400$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3536,26953,27903,27904,65309</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/1359314$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Ramos, A.</creatorcontrib><creatorcontrib>Filtvedt, W.O.</creatorcontrib><creatorcontrib>Lindholm, D.</creatorcontrib><creatorcontrib>Ramachandran, P.A.</creatorcontrib><creatorcontrib>Rodríguez, A.</creatorcontrib><creatorcontrib>del Cañizo, C.</creatorcontrib><title>Deposition reactors for solar grade silicon: A comparative thermal analysis of a Siemens reactor and a fluidized bed reactor</title><title>Journal of crystal growth</title><description>Polysilicon production costs contribute approximately to 25–33% of the overall cost of the solar panels and a similar fraction of the total energy invested in their fabrication. Understanding the energy losses and the behaviour of process temperature is an essential requirement as one moves forward to design and build large scale polysilicon manufacturing plants. In this paper we present thermal models for two processes for poly production, viz., the Siemens process using trichlorosilane (TCS) as precursor and the fluid bed process using silane (monosilane, MS). We validate the models with some experimental measurements on prototype laboratory reactors relating the temperature profiles to product quality. A model sensitivity analysis is also performed, and the effects of some key parameters such as reactor wall emissivity and gas distributor temperature, on temperature distribution and product quality are examined. The information presented in this paper is useful for further understanding of the strengths and weaknesses of both deposition technologies, and will help in optimal temperature profiling of these systems aiming at lowering production costs without compromising the solar cell quality.
•Temperature control in the CVD processes for SoGSi production is essential.•The heat loss problem associated with polysilicon CVD is addressed.•CFD models for a Siemens and FBR prototypes are developed.•The CFD models developed give us reasonable estimates of the temperature distribution.•CFD models become a tool for design and will help in optimal temperature profiling of these systems.</description><subject>A1. CFD modelling</subject><subject>A3. CVD reactors</subject><subject>A3. CVD reactors B2. Polysilicon B2. Solar grade silicon A3. Siemens process Fluidized bed reactor A1. CFD modelling</subject><subject>A3. Siemens process</subject><subject>B2. Polysilicon</subject><subject>B2. Solar grade silicon</subject><subject>Deposition</subject><subject>Energia solar</subject><subject>Energia solar fotovoltaica</subject><subject>Energia solar tèrmica</subject><subject>Energies</subject><subject>Fluidized bed reactor</subject><subject>Industrial engineering</subject><subject>Manufacturing engineering</subject><subject>Mathematical models</subject><subject>Production costs</subject><subject>Reactors</subject><subject>Sensitivity analysis</subject><subject>Solar energy</subject><subject>Thermal analysis</subject><subject>Àrees temàtiques de la UPC</subject><issn>0022-0248</issn><issn>1873-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>XX2</sourceid><recordid>eNqFkUFv1DAQhSMEEkvhLyCLE5eEsR0nDieq0lKkShwoZ8uMJ61XSbzY3kqL-PF1tFtx7GFs2fO-J49fVb3n0HDg3adts8V4SHcxNAK4akA3IOSLasN1L2sFIF5Wm7KKGkSrX1dvUtoCFJLDpvr3lXYh-ezDwiJZzCEmNobIUphsZHfROmLJTx7D8pmdMwzzzkab_QOxfE9xthOzi50OyScWRmbZT08zLenJrXRduR2nvXf-Lzn2u9Sp97Z6Ndop0bvTflb9urq8vbiub358-35xflOj6lSuB81hsANXCsdxRLC6Ez1Y24PGwZGTo3YC0UoH5DRXg1QcW9d32DnVcZJn1Yejb0jZm4Q-E96XgRbCbLgsAG-LiB9FmPZoIiFFtNkE6_8f1hLQCyM72fKhMB-PzC6GP3tK2cw-IU2TXSjsk-Gad6BE28si7U72MaQUaTS76GcbD4aDWXM0W_OUo1lzNKBNybGAX44glR968BTXAWhBcj6u73fBP2fxCFyrq54</recordid><startdate>20151201</startdate><enddate>20151201</enddate><creator>Ramos, A.</creator><creator>Filtvedt, W.O.</creator><creator>Lindholm, D.</creator><creator>Ramachandran, P.A.</creator><creator>Rodríguez, A.</creator><creator>del Cañizo, C.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>XX2</scope><scope>OTOTI</scope></search><sort><creationdate>20151201</creationdate><title>Deposition reactors for solar grade silicon: A comparative thermal analysis of a Siemens reactor and a fluidized bed reactor</title><author>Ramos, A. ; Filtvedt, W.O. ; Lindholm, D. ; Ramachandran, P.A. ; Rodríguez, A. ; del Cañizo, C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c565t-98109a9155cfffc0a86270aa708c9ded3f8d2cca3d0ed8159351c4d76c6d561e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>A1. CFD modelling</topic><topic>A3. CVD reactors</topic><topic>A3. CVD reactors B2. Polysilicon B2. Solar grade silicon A3. Siemens process Fluidized bed reactor A1. CFD modelling</topic><topic>A3. Siemens process</topic><topic>B2. Polysilicon</topic><topic>B2. Solar grade silicon</topic><topic>Deposition</topic><topic>Energia solar</topic><topic>Energia solar fotovoltaica</topic><topic>Energia solar tèrmica</topic><topic>Energies</topic><topic>Fluidized bed reactor</topic><topic>Industrial engineering</topic><topic>Manufacturing engineering</topic><topic>Mathematical models</topic><topic>Production costs</topic><topic>Reactors</topic><topic>Sensitivity analysis</topic><topic>Solar energy</topic><topic>Thermal analysis</topic><topic>Àrees temàtiques de la UPC</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ramos, A.</creatorcontrib><creatorcontrib>Filtvedt, W.O.</creatorcontrib><creatorcontrib>Lindholm, D.</creatorcontrib><creatorcontrib>Ramachandran, P.A.</creatorcontrib><creatorcontrib>Rodríguez, A.</creatorcontrib><creatorcontrib>del Cañizo, C.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Recercat</collection><collection>OSTI.GOV</collection><jtitle>Journal of crystal growth</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ramos, A.</au><au>Filtvedt, W.O.</au><au>Lindholm, D.</au><au>Ramachandran, P.A.</au><au>Rodríguez, A.</au><au>del Cañizo, C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Deposition reactors for solar grade silicon: A comparative thermal analysis of a Siemens reactor and a fluidized bed reactor</atitle><jtitle>Journal of crystal growth</jtitle><date>2015-12-01</date><risdate>2015</risdate><volume>431</volume><issue>C</issue><spage>1</spage><epage>9</epage><pages>1-9</pages><issn>0022-0248</issn><eissn>1873-5002</eissn><abstract>Polysilicon production costs contribute approximately to 25–33% of the overall cost of the solar panels and a similar fraction of the total energy invested in their fabrication. Understanding the energy losses and the behaviour of process temperature is an essential requirement as one moves forward to design and build large scale polysilicon manufacturing plants. In this paper we present thermal models for two processes for poly production, viz., the Siemens process using trichlorosilane (TCS) as precursor and the fluid bed process using silane (monosilane, MS). We validate the models with some experimental measurements on prototype laboratory reactors relating the temperature profiles to product quality. A model sensitivity analysis is also performed, and the effects of some key parameters such as reactor wall emissivity and gas distributor temperature, on temperature distribution and product quality are examined. The information presented in this paper is useful for further understanding of the strengths and weaknesses of both deposition technologies, and will help in optimal temperature profiling of these systems aiming at lowering production costs without compromising the solar cell quality.
•Temperature control in the CVD processes for SoGSi production is essential.•The heat loss problem associated with polysilicon CVD is addressed.•CFD models for a Siemens and FBR prototypes are developed.•The CFD models developed give us reasonable estimates of the temperature distribution.•CFD models become a tool for design and will help in optimal temperature profiling of these systems.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jcrysgro.2015.08.023</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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subjects | A1. CFD modelling A3. CVD reactors A3. CVD reactors B2. Polysilicon B2. Solar grade silicon A3. Siemens process Fluidized bed reactor A1. CFD modelling A3. Siemens process B2. Polysilicon B2. Solar grade silicon Deposition Energia solar Energia solar fotovoltaica Energia solar tèrmica Energies Fluidized bed reactor Industrial engineering Manufacturing engineering Mathematical models Production costs Reactors Sensitivity analysis Solar energy Thermal analysis Àrees temàtiques de la UPC |
title | Deposition reactors for solar grade silicon: A comparative thermal analysis of a Siemens reactor and a fluidized bed reactor |
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